Potassium formate synthesis
- Product Name:Potassium formate
- CAS Number:590-29-4
- Molecular formula:CHKO2
- Molecular Weight:84.12
617-86-7
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124-38-9
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$214.00/14L
597-52-4
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$47.03/1g
994-49-0
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590-29-4
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Yield:590-29-4 60%
Reaction Conditions:
with potassium fluoride;dodecacarbonyl-triangulo-triruthenium in water at 80; under 5171.62 Torr; for 13 h;Inert atmosphere;Autoclave;Green chemistry;
Steps:
4.8. One-pot synthesis of potassium formate
General procedure: The reaction was carried out in a 100-mL stainless steel Parrautoclave. The reactor was loaded with [Ru3(CO)12] (1.0 mg1.6 x 10-3 mmol), Et3SiH (360 mg 3.06 mmol), KF (179.8 mg,3.06 mmol), 10 mL of MeCN or water, and CO2 (100 psi), and heatedat 80 °C for 13 h. When MeCN was used as the solvent, the finalmixture was filtered over celite and analyzed by GC/MS, but whenthe reaction was performed in water, it was analyzed by 1H NMR(22 °C, 300 MHz, D2O) 8.40 ppm (KOC(O)-H). Isolated yield 60%.
References:
Jurado-Vázquez, Tamara;Ortiz-Cervantes, Carmen;García, Juventino J. [Journal of Organometallic Chemistry,2016,vol. 823,p. 8 - 13]
124-38-9
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$214.00/14L
590-29-4
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$6.00/100g
617-86-7
530 suppliers
$9.00/5g
124-38-9
130 suppliers
$214.00/14L
994-49-0
111 suppliers
$16.00/1g
590-29-4
401 suppliers
$6.00/100g
298-14-6
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590-29-4
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$6.00/100g
617-86-7
530 suppliers
$9.00/5g
124-38-9
130 suppliers
$214.00/14L
358-43-0
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994-49-0
111 suppliers
$16.00/1g
590-29-4
401 suppliers
$6.00/100g