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ChemicalBook CAS DataBase List Norethindrone-3-ethyldienolether
96487-85-3

Norethindrone-3-ethyldienolether synthesis

3synthesis methods
-

Yield:96487-85-3 92%

Reaction Conditions:

with toluene-4-sulfonic acid in tetrahydrofuran at 25; for 12 h;Temperature;

Steps:

1.1 1.1 3-ethoxy-17α-ethynyl-19-desmethylpregna-3,5-diene-17β-ol (2)

Compound 1 (15 g, 0.05 mol) was dissolved in THF (150 ml) and added to the reaction flask, Then triethyl orthoformate (14.8 g, 0.1 mol) was added, P-toluenesulfonic acid (0.15 g, 0.8 mmol). The reaction solution was stirred at 25 ° C for 12 hours, Pyridine (3 ml) was added, The majority of the solvent was distilled off under reduced pressure, Cooling filter, Dried product 15g, Yield 92%.

References:

CN105017365,2017,B Location in patent:Paragraph 0031-0033; 0044-0046; 0057-0059

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