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ChemicalBook CAS DataBase List N-BENZYL-BIS(2-CHLOROETHYL)AMINE HYDROCHLORIDE
10429-82-0

N-BENZYL-BIS(2-CHLOROETHYL)AMINE HYDROCHLORIDE synthesis

2synthesis methods
-

Yield:10429-82-0 100%

Reaction Conditions:

with thionyl chloride in dichloromethane at 20;

Steps:

9A.b b) N-Benzyl-2-chloro-N-(2-chloroethyl)ethanam me hydrochloride.

Sulfurous dichloride (35.8mL, 482 mmol) in anhydride DCM (60 mL), was added to a cold solution of 2,2’-(benzylazanediyl)diethanol (obtained in step a, 31.4 g, 160 mmol) in DCM (200 mL) and the reaction mixture was stirred at rt. overnight. The solvent was removed to dryness to give the title compound (47.2 g, 100% yield), that was used in the next step without further purification.HPLC-MS (Method A): Ret, 2.34 mm; ESl-MS m/z, 262 (M+1).

References:

WO2017/16669,2017,A1 Location in patent:Page/Page column 201

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