METHYL 4-(3-PYRIDINYL)BENZOATE synthesis
- Product Name:METHYL 4-(3-PYRIDINYL)BENZOATE
- CAS Number:90395-47-4
- Molecular formula:C13H11NO2
- Molecular Weight:213.23
626-60-8
374 suppliers
$13.00/5g
99768-12-4
368 suppliers
$10.00/1g
90395-47-4
20 suppliers
$311.00/1g
Yield:90395-47-4 92%
Reaction Conditions:
Stage #1: 3-Chloropyridine;4-methoxycarbonylphenylboronic acidwith palladium diacetate;(R)-6-dicyclohexylphoshino-6'-diphenylphosphino-3,3'-dimethoxy-2,2',4,4'-tetramethyl-1,1'-biphenyl in dodecane;butan-1-ol at 25; for 0.0833333 h;Inert atmosphere;Glovebox;Suzuki-Miyaura Coupling;
Stage #2: with cesiumhydroxide monohydrate in dodecane;water;butan-1-ol at 80; for 4 h;Glovebox;Inert atmosphere;Suzuki-Miyaura Coupling;
References:
Yang, Junfeng;Liu, Sijia;Zheng, Jian-Feng;Zhou, Jianrong [European Journal of Organic Chemistry,2012,# 31,p. 6248 - 6259,12] Location in patent:supporting information
619-42-1
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$7.00/10g
1692-25-7
486 suppliers
$5.00/1g
90395-47-4
20 suppliers
$311.00/1g
619-44-3
309 suppliers
$6.00/10g
59020-10-9
81 suppliers
$7.00/1g
90395-47-4
20 suppliers
$311.00/1g
619-42-1
362 suppliers
$7.00/10g
89878-14-8
393 suppliers
$6.00/1g
90395-47-4
20 suppliers
$311.00/1g
619-42-1
362 suppliers
$7.00/10g
59020-10-9
81 suppliers
$7.00/1g
90395-47-4
20 suppliers
$311.00/1g