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ChemicalBook CAS DataBase List 1,1-Dimethylethyl 10,10-dimethyl-8-oxo-3,9-dioxa-2,7-diazaundecanoate
1243021-74-0

1,1-Dimethylethyl 10,10-dimethyl-8-oxo-3,9-dioxa-2,7-diazaundecanoate synthesis

1synthesis methods
36016-38-3 Synthesis
tert-Butyl N-hydroxycarbamate

36016-38-3
355 suppliers
$6.00/5g

83948-53-2 Synthesis
tert-Butyl 3-bromopropylcarbamate

83948-53-2
195 suppliers
$6.00/1g

1,1-Dimethylethyl 10,10-dimethyl-8-oxo-3,9-dioxa-2,7-diazaundecanoate

1243021-74-0
35 suppliers
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Yield:1243021-74-0 42%

Reaction Conditions:

Stage #1: tert-Butyl N-hydroxycarbamatewith sodium hydride in tetrahydrofuran;mineral oil at 0; for 0.5 h;
Stage #2: 3-bromopropylamine tert-butylcarbamate in tetrahydrofuran;mineral oil at 0 - 20;

References:

Klee, Nina;Wong, Pui Ee;Baragana, Beatriz;Mazouni, Farah El;Phillips, Margaret A.;Barrett, Michael P.;Gilbert, Ian H. [Bioorganic and Medicinal Chemistry Letters,2010,vol. 20,# 15,p. 4364 - 4366] Location in patent:supporting information; experimental part

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