Chloro(dodecyl)dimethylsilane synthesis
- Product Name:Chloro(dodecyl)dimethylsilane
- CAS Number:66604-31-7
- Molecular formula:C14H31ClSi
- Molecular Weight:262.93
![Ethanamine, N-[(3,5-dichlorophenyl)methylene]-2,2-diethoxy-](/CAS/20210305/GIF/1000210-73-0.gif)
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Yield: 89.1%
Reaction Conditions:
with tetrachloromethane;palladium dichloride at 20; for 2 h;Inert atmosphere;
Steps:
Chlorododecyldimethylsilane 6(12,1)
General procedure: Typical procedure for the synthesis of 6(m,1): Under nitrogen, PdCl2 (23.3 mg, 0.131 mmol) was added to 5(10,1) (2.41 g, 12.0 mmol) in dry CCl4 (20.0 mL, 206 mmol) and stirred for 2 h. The solvent was removed under reduced pressure to give a colorless liquid with Pd precipitate. Purification of the crude product by Kugelrohr distillation apparatus (< 10 mmHg, 180 °C)
References:
Hirose, Takuji;Miyazaki, Yutaro;Watabe, Mizuki;Akimoto, Sho;Tachikawa, Tatsuya;Kodama, Koichi;Yasutake, Mikio [Tetrahedron,2015,vol. 71,# 29,p. 4714 - 4721] Location in patent:supporting information
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