ChemicalBook CAS DataBase List Decane

Decane synthesis

12synthesis methods

Product Name:Decane
CAS Number:124-18-5
Molecular formula:C10H22
Molecular Weight:142.28

1942-46-7 Synthesis

1942-46-7
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$6.00/250mg

124-18-5
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$24.00/25mL

Yield:124-18-5 96 %Chromat.

Reaction Conditions:

with C₅H₁₄NO⁽¹⁺⁾*C₁₀H₁₂NO₄S^(1-)*Pd;hydrogen in glycerol at 80; under 2250.23 Torr; for 2 h;Inert atmosphere;Schlenk technique;

Steps:

2.5. General procedure for Pd-catalyzed hydrogenation in glycerol

General procedure: In a Fisher-Porter bottle (working from 1 to 3 bar total pressure) oran autoclave (working from 3 to 20 bar total pressure), the appropriate substrate (1 mmol for 1 mol % of catalyst or 10 mmol for 0.1 mol% of catalyst) was added to 1 mL of preformed nanoparticles (2.85 mg of Pd) in glycerol under argon. The reaction mixture was put under vacuum and then pressurized with H2 at the convenient pressure, heated up at 80 °C and stirred for the appropriate time; then cooled down to room temperature before extraction. Organic products were extracted from glycerol by a biphasic methodology, adding dichloromethane (5×3 mL); organic phases were collected and solvent removed under vacuum. Conversion and yields were determined by GC using decane as internal standard. The obtained products were characterized by GC-MS data and 1H and 13C NMR and compared to literature reports to confirm spectral identity (see Supplementary Material).

References:

Garg, Garima;Foltran, Stéphanie;Favier, Isabelle;Pla, Daniel;Medina-González, Yaocihuatl;Gómez, Montserrat [Catalysis Today,2020,vol. 346,p. 69 - 75]