Cyclohexene oxide synthesis
- Product Name:Cyclohexene oxide
- CAS Number:286-20-4
- Molecular formula:C6H10O
- Molecular Weight:98.14
110-83-8
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$11.00/25g
930-68-7
259 suppliers
$9.00/1g
931-17-9
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$11.00/5g
286-20-4
204 suppliers
$14.00/25mL
822-67-3
108 suppliers
$49.60/1g
Yield:286-20-4 98%
Reaction Conditions:
with tert.-butylhydroperoxide;C10H10MoN2O7 in water;1,2-dichloro-ethane at 80;Overall yield = 78percent;Reagent/catalyst;
Steps:
2.4.2 Epoxidation reactions
General procedure: The catalytic abilities of all complexes were studied for epoxidation of alkenes, i.e. styrene and cyclohexene, and monoterpenes, i.e. S(-)-limonene and (-)-α-pinene, using aqueous 30% H2O2 or 5.5M decane solution of tert-butyl hydroperoxide. Different amounts of catalysts and oxidants were also tested to optimize reaction conditions. All reactions were run in 1,2-dichloroethane (DCE) at 80°C and monitored by GC using 1:100:200M ratio of catalyst, substrate and oxidant, respectively. The yields were recorded as GC yield based on the starting substrate. The identity of oxidation products were confirmed by GC-MS.
References:
Karman, Marta;Romanowski, Grzegorz;Wera, Micha? [Polyhedron,2020,vol. 187]
110-83-8
308 suppliers
$11.00/25g
286-20-4
204 suppliers
$14.00/25mL
110-83-8
308 suppliers
$11.00/25g
930-68-7
259 suppliers
$9.00/1g
286-20-4
204 suppliers
$14.00/25mL
108-94-1
546 suppliers
$12.00/50g
108-93-0
429 suppliers
$11.00/25g
110-83-8
308 suppliers
$11.00/25g
930-68-7
259 suppliers
$9.00/1g
4845-05-0
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286-20-4
204 suppliers
$14.00/25mL
110-83-8
308 suppliers
$11.00/25g
930-68-7
259 suppliers
$9.00/1g
286-20-4
204 suppliers
$14.00/25mL
822-67-3
108 suppliers
$49.60/1g