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ChemicalBook CAS DataBase List 4-NITROSOANISOLE
1516-21-8

4-NITROSOANISOLE synthesis

12synthesis methods
5720-07-0 Synthesis
4-Methoxyphenylboronic acid

5720-07-0
462 suppliers
$6.00/5g

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Yield:1516-21-8 130 mg

Reaction Conditions:

Stage #1: 4-methoxybenzeneboronic acidwith potassium hydrogen difluoride in methanol;lithium hydroxide monohydrate at 0 - 20; for 0.0333333 h;Inert atmosphere;
Stage #2: with nitrosonium tetrafluoroborate in acetonitrile at 20; for 0.00833333 h;regioselective reaction;

References:

Molander, Gary A.;Cavalcanti, Livia N. [Journal of Organic Chemistry,2012,vol. 77,# 9,p. 4402 - 4413] Location in patent:experimental part

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