4'-AMINOBIPHENYL-3-CARBONITRILE synthesis
- Product Name:4'-AMINOBIPHENYL-3-CARBONITRILE
- CAS Number:443998-73-0
- Molecular formula:C13H10N2
- Molecular Weight:194.23
69113-59-3
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106-40-1
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$12.00/5g
443998-73-0
31 suppliers
$45.00/50mg
Yield:443998-73-0 89%
Reaction Conditions:
Stage #1: 3-iodobenzonitrilewith TurboGrignard in tetrahydrofuran at -20;Inert atmosphere;
Stage #2: with lithium chlorozincate in tetrahydrofuran at 25;Inert atmosphere;
Stage #3: 4-bromo-anilinewith bis(dibenzylideneacetone)-palladium(0);ruphos in tetrahydrofuran at 25; for 0.166667 h;Inert atmosphere;Negishi cross-coupling reaction;
References:
Kienle, Marcel;Knochel, Paul [Organic Letters,2010,vol. 12,# 12,p. 2702 - 2705] Location in patent:supporting information; experimental part
150255-96-2
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106-40-1
475 suppliers
$12.00/5g
443998-73-0
31 suppliers
$45.00/50mg
4471-22-1
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766-84-7
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$9.00/10g
443998-73-0
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$45.00/50mg
62-53-3
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$10.00/1g
443998-73-0
31 suppliers
$45.00/50mg
6952-59-6
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214360-73-3
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$8.00/1g
443998-73-0
31 suppliers
$45.00/50mg