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355368-67-1

2-CHLORO-5-(5-FORMYL-FURAN-2-YL)BENZOIC ACID METHYL ESTER synthesis

1synthesis methods
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Yield:355368-67-1 67.7%

Reaction Conditions:

Stage #1: methyl 2-chloro-5-aminobenzoatewith hydrogenchloride;sodium nitrite in water at 0;
Stage #2: furfuralwith copper dichloride in water at 0 - 20;

References:

He, Lingyan;Zhang, Liang;Liu, Xiaofeng;Li, Xianghua;Zheng, Mingyue;Li, HongLin;Yu, Kunqian;Chen, Kaixian;Shen, Xu;Jiang, Hualiang;Liu, Hong [Journal of Medicinal Chemistry,2009,vol. 52,# 8,p. 2465 - 2481] Location in patent:experimental part