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ChemicalBook CAS DataBase List 2-DI-TERT-BUTYLPHOSPHINO-3,4,5,6-TETRAM&
857356-94-6

2-DI-TERT-BUTYLPHOSPHINO-3,4,5,6-TETRAM& synthesis

2synthesis methods
-

Yield:-

Steps:

Multi-step reaction with 2 steps
1.1: 85 percent / bromine; ZnCl2 / acetic acid / 14 h / 20 °C
2.1: magnesium; 1,2-dibromoethane / tetrahydrofuran / 1.5 h / 60 °C
2.2: tetrahydrofuran / 1.5 h / 60 °C
2.3: 62 percent / CuCl / tetrahydrofuran / 40 h / 75 °C

References:

Burgos, Carlos H.;Barder, Timothy E.;Huang, Xiaohua;Buchwald, Stephen L. [Angewandte Chemie - International Edition,2006,vol. 45,# 26,p. 4321 - 4326]

FullText

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