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ChemicalBook CAS DataBase List 2-(AMINOCARBONYL)NICOTINIC ACID
5860-70-8

2-(AMINOCARBONYL)NICOTINIC ACID synthesis

2synthesis methods
-

Yield:5860-70-8 81.9%

Reaction Conditions:

with ammonium hydroxide in water; for 2.5 h;Cooling with ice;

Steps:

1.B Step B: Preparation of 2-carbamoylpyridine-3-carboxylic acid

Place 13.6g (200mmol) of 25% ammonia water in a 100mL eggplant-shaped flask, slowly add 7.46g (50mmol) of 2,3-pyridinedicarboxylic anhydride under ice-water bath conditions, stir for 2.5h, heat up to 40°C, and continue The reaction was carried out for 3.5h, vacuumed after cooling, and the pH value was adjusted to about 5 with concentrated hydrochloric acid, and a large amount of white solid was precipitated, which was filtered and dried to obtain 6.8g of 2-carbamoylpyridine-3-carboxylic acid white solid, the yield was 81.9%.

References:

CN113979936,2022,A Location in patent:Paragraph 0036; 0040-0041

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