2-Allyloxyphenylboronic acid synthesis
- Product Name:2-Allyloxyphenylboronic acid
- CAS Number:151414-76-5
- Molecular formula:C9H11BO3
- Molecular Weight:177.99
5419-55-6
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$12.00/5g
60333-75-7
13 suppliers
$444.00/1g
151414-76-5
20 suppliers
$435.00/250mg
Yield:151414-76-5 48%
Reaction Conditions:
with n-butyllithium in tetrahydrofuran;hexane;BuLi in hexane is added to a soln. of ether-compd. in THF at -78°C, the mixt. is stirred for 1 h under N2, triisopropyl borate is added and the mixt. is stirred for 1,5 h, then warmed to room temp, HCl and Et2O is added; the organic layer is separated and washed with HCl and water, the solvent is evaporated, the residue is stirred with light petroleum at 0°C, the ppt. is washed with ice cold light petroleum, crystn. from CHCl3-light petroleum, elem. anal.;
References:
Morgan, Jacqueline;Pinhey, John T. [Journal of the Chemical Society. Perkin transactions I,1993,# 14,p. 1673 - 1676]
60333-75-7
13 suppliers
$444.00/1g
151414-76-5
20 suppliers
$435.00/250mg