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ChemicalBook CAS DataBase List 2,5-Anhydro-D-mannitol Tetraacetate
65729-88-6

2,5-Anhydro-D-mannitol Tetraacetate synthesis

6synthesis methods
-

Yield:65729-88-6 80%

Reaction Conditions:

Stage #1: (+)-D-glucosamine hydrochloridewith sodium nitrite in acetic acid at 0; for 2 h;
Stage #2: with sodium tetrahydroborate in water at 20; for 1 h;
Stage #3: acetic anhydridewith pyridine at 20;Further stages.;

References:

Cassel, Stephanie;Debaig, Catherine;Benvegnu, Thierry;Chaimbault, Patrick;Lafosse, Michel;Plusquellec, Daniel;Rollin, Patrick [European Journal of Organic Chemistry,2001,# 5,p. 875 - 896]