3H-Pyrido[2,1-c][1,4]oxaazacyclotricosine-1,7,19,20,21(4H,8H,23H)-pentone, 15-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-3-[(1E)-2-[(1R,3R,4R)-4-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-3-methoxycyclohexyl]-1-methylethenyl]-5,6,11,12,13,14,15,16,17,18,24,25,26,26a-tetradecahydro-5-hydroxy-14,16-dimethoxy-4,10,12,18-tetramethyl-8-(2-propen-1-yl)-, (3S,4R,5S,8R,9E,12S,14S,15R,16S,18R,26aS)- synthesis
- Product Name:3H-Pyrido[2,1-c][1,4]oxaazacyclotricosine-1,7,19,20,21(4H,8H,23H)-pentone, 15-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-3-[(1E)-2-[(1R,3R,4R)-4-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-3-methoxycyclohexyl]-1-methylethenyl]-5,6,11,12,13,14,15,16,17,18,24,25,26,26a-tetradecahydro-5-hydroxy-14,16-dimethoxy-4,10,12,18-tetramethyl-8-(2-propen-1-yl)-, (3S,4R,5S,8R,9E,12S,14S,15R,16S,18R,26aS)-
- CAS Number:197250-11-6
- Molecular formula:C66H101NO12Si2
- Molecular Weight:1156.68
197250-10-5
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197250-11-6
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Yield:197250-11-6 100%
Reaction Conditions:
with 3,3-dimethyldioxirane in acetone at -50 - -26; for 2.16667 h;Oxidation;fragmentation;
References:
Ireland, Robert E.;Liu, Longbin;Roper, Thomas D.;Gleason, James L. [Tetrahedron,1997,vol. 53,# 39,p. 13257 - 13284]