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ChemicalBook CAS DataBase List 3'-O-methylguanosine
10300-27-3

3'-O-methylguanosine synthesis

9synthesis methods
-

Yield:-

Steps:

Multi-step reaction with 3 steps
1: 1.) hexamethyldisilazane, chlorotrimethylsilane; 2.) hexamethyldisilazane, CF3SO3SiMe3, NH3 / 1.) reflux, 16 h; 2.) 150 deg C, 3 d (sealed bomb)
2: 47 percent / SnCl2*2H2O / dimethylformamide; 1,2-dimethoxy-ethane / 50 °C
3: 92 percent / adenosine deaminase / dimethylsulfoxide; H2O / 72 h / Ambient temperature; 0.1M sodium phosphate buffer

References:

Robins, Morris J.;Hansske, Fritz;Bernier, Salwa E. [Canadian Journal of Chemistry,1981,vol. 59,p. 3360 - 3364]

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