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ChemicalBook >> CAS DataBase List >> Trimethylaluminium

Trimethylaluminium

Trimethylaluminium price.
  • $54.5 - $8756
  • Product name: Trimethylaluminium
  • CAS: 75-24-1
  • MF: C3H9Al
  • MW: 72.09
  • EINECS:200-853-0
  • MDL Number:MFCD00008252
  • Synonyms:trimethyl-alane ;Trimethylaluminum solution;Trimethylaluminiummincolorlessliquid;trimethylaluminum steel flask 0.3 L (net ~150 G);TrimethylaluminumelecgrPURATREMcolorlessliq;Trimethylalumine;TRIMETHYLALUMINUM FOR CAMBRIDGE NANOTECH INC ALD SYSTEMS;TRIMETHYLALUMINUM, 2.0M SOLUTION IN HEXA NES
32 prices
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  • Alfa Aesar
  • Biorbyt Ltd
  • Oakwood
  • Sigma-Aldrich
  • Strem Chemicals
  • TRC
  • Usbiological
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  • ManufacturerAlfa Aesar
  • Product number042836
  • Product descriptionTrimethylaluminum 25% w/w in hexane
  • Packaging100ml
  • Price$54.5
  • Updated2021-12-16
  • Buy
  • ManufacturerAlfa Aesar
  • Product number042836
  • Product descriptionTrimethylaluminum 25% w/w in hexane
  • Packaging500ml
  • Price$178
  • Updated2021-12-16
  • Buy
  • ManufacturerAlfa Aesar
  • Product number042836
  • Product descriptionTrimethylaluminum 25% w/w in hexane
  • Packaging*4x500ml
  • Price$504
  • Updated2021-12-16
  • Buy
  • ManufacturerBiorbyt Ltd
  • Product numberorb529016
  • Product descriptionATM
  • Packaging10μg
  • Price$227.8
  • Updated2021-12-16
  • Buy
  • ManufacturerBiorbyt Ltd
  • Product numberorb599064
  • Product descriptionATM
  • Packaging10μg
  • Price$290.7
  • Updated2021-12-16
  • Buy
  • ManufacturerOakwood
  • Product number098855
  • Product descriptionTrimethylaluminum
  • Packaging25g
  • Price$140
  • Updated2021-12-16
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number198048
  • Product descriptionTrimethylaluminum solution 2.0 M in toluene
  • Packaging4x25ml
  • Price$84.7
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number198048
  • Product descriptionTrimethylaluminum solution 2.0 M in toluene
  • Packaging100ml
  • Price$89.2
  • Updated2024-03-01
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  • ManufacturerSigma-Aldrich
  • Product number379239
  • Product descriptionTrimethylaluminum solution 2.0M in heptane
  • Packaging100ml
  • Price$122
  • Updated2024-03-01
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  • ManufacturerSigma-Aldrich
  • Product number268569
  • Product descriptionTrimethylaluminum solution 2.0M in hexanes
  • Packaging100ml
  • Price$137
  • Updated2024-03-01
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  • ManufacturerSigma-Aldrich
  • Product number257222
  • Product descriptionTrimethylaluminum 97%
  • Packaging100g
  • Price$312
  • Updated2024-03-01
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  • ManufacturerSigma-Aldrich
  • Product number198048
  • Product descriptionTrimethylaluminum solution 2.0 M in toluene
  • Packaging800ml
  • Price$450
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number198048
  • Product descriptionTrimethylaluminum solution 2.0 M in toluene
  • Packaging1l
  • Price$501
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number379239
  • Product descriptionTrimethylaluminum solution 2.0M in heptane
  • Packaging800ml
  • Price$787
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number268569
  • Product descriptionTrimethylaluminum solution 2.0M in hexanes
  • Packaging800ml
  • Price$875
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number198048
  • Product descriptionTrimethylaluminum solution 2.0 M in toluene
  • Packaging8l
  • Price$1930
  • Updated2024-03-01
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Alfa Aesar 042836 Trimethylaluminum 25% w/w in hexane 100ml $54.5 2021-12-16 Buy
Alfa Aesar 042836 Trimethylaluminum 25% w/w in hexane 500ml $178 2021-12-16 Buy
Alfa Aesar 042836 Trimethylaluminum 25% w/w in hexane *4x500ml $504 2021-12-16 Buy
Biorbyt Ltd orb529016 ATM 10μg $227.8 2021-12-16 Buy
Biorbyt Ltd orb599064 ATM 10μg $290.7 2021-12-16 Buy
Oakwood 098855 Trimethylaluminum 25g $140 2021-12-16 Buy
Sigma-Aldrich 198048 Trimethylaluminum solution 2.0 M in toluene 4x25ml $84.7 2024-03-01 Buy
Sigma-Aldrich 198048 Trimethylaluminum solution 2.0 M in toluene 100ml $89.2 2024-03-01 Buy
Sigma-Aldrich 379239 Trimethylaluminum solution 2.0M in heptane 100ml $122 2024-03-01 Buy
Sigma-Aldrich 268569 Trimethylaluminum solution 2.0M in hexanes 100ml $137 2024-03-01 Buy
Sigma-Aldrich 257222 Trimethylaluminum 97% 100g $312 2024-03-01 Buy
Sigma-Aldrich 198048 Trimethylaluminum solution 2.0 M in toluene 800ml $450 2024-03-01 Buy
Sigma-Aldrich 198048 Trimethylaluminum solution 2.0 M in toluene 1l $501 2024-03-01 Buy
Sigma-Aldrich 379239 Trimethylaluminum solution 2.0M in heptane 800ml $787 2024-03-01 Buy
Sigma-Aldrich 268569 Trimethylaluminum solution 2.0M in hexanes 800ml $875 2024-03-01 Buy
Sigma-Aldrich 198048 Trimethylaluminum solution 2.0 M in toluene 8l $1930 2024-03-01 Buy

Properties

Melting point :15 °C
Boiling point :126 °C
Density :0.81 g/mL at 25 °C
vapor pressure :69.3 mmHg ( 60 °C)
Flash point :40 °F
storage temp. :0-6°C
solubility :Soluble in aromatic, saturated aliphatic and cycloaliphatic hydrocarbons.
form :Liquid
color :Clear colorless
Specific Gravity :0.688
Odor :Corrosive odor and "taste" may be detectable from trimethylaluminum fires
Water Solubility :REACTS
Sensitive :Air & Moisture Sensitive
Hydrolytic Sensitivity :9: reacts extremely rapidly with atmospheric moisture - may be pyrophoric - glove box or sealed system required
BRN :3587197
Exposure limits :ACGIH: TWA 50 ppm (Skin)
OSHA: TWA 500 ppm(1800 mg/m3)
NIOSH: IDLH 1100 ppm; TWA 50 ppm(180 mg/m3) InChIKey :JLTRXTDYQLMHGR-UHFFFAOYSA-N
CAS DataBase Reference :75-24-1(CAS DataBase Reference)
NIST Chemistry Reference :Trimethylaluminum(75-24-1)
EPA Substance Registry System :Aluminum, trimethyl- (75-24-1)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H250 Catches fire spontaneously if exposed to air Pyrophoric liquids; Pyrorophoric solids Category 1 Danger GHS hazard pictograms P210, P222, P280, P302+P334,P370+P378, P422
H260 In contact with water releases flammable gases which may ignite spontaneously Substances And Mixtures Which, In Contact With Water,Emit Flammable Gases Category 1 Danger GHS hazard pictograms P223, P231+P232, P280, P335+ P334,P370+P378, P402+P404, P501
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P222 Do not allow contact with air.
P231+P232 Handle under inert gas. Protect from moisture.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

Trimethylaluminum is used as an intermediate in the production of methylaluminoxane. It is employed as a methylating agent in synthetic chemistry. It is also used in semiconductor fabrication to deposit thin film. It is involved in Tebbe's reagent, which is used for the methylenation of esters and ketones. It acts as an activator for Ziegler-Natta catalysts for olefin polymerization. It plays an important role in the Oppenauer oxidation reaction to prepare aldehydes and ketones. Further, it is used as plating agents and surface treating agents.

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