ETHYNYLMAGNESIUM CHLORIDE

$75.3 - $495.51
Product name: ETHYNYLMAGNESIUM CHLORIDE
CAS: 65032-27-1
MF: C2HClMg
MW: 84.79
EINECS:
MDL Number:MFCD00075343
Synonyms:ETHYNYLMAGNESIUM CHLORIDE;Ethynylmagnesium chloride, 1.1M solution in THF/toluene;Ethynylmagnesium chloride solution;ETHYNYLMAGNESIUM CHLORIDE, 0.5M SOLUTION IN TETRAHYDROFURAN;Ethynylmagnesium chloride, 0.6M solution in THF/Toluene;EthynylMagnesiuM chloride, 0.6 M solution in THF/toluene, J&KSeal;Ethynylmagnesium chloride solution 0.5 in THF;Ethynylmagnesium chloride, 0.6M solution in THF/Toluene, AcroSeal

Price3 Properties Safety Information Description

3 prices

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Brand

Package

Manufacturer	Product number	Product description	Packaging	Price	Updated	Buy
American Custom Chemicals Corporation	ING0010566	ETHYNYLMAGNESIUM CHLORIDE 95.00%	5MG	$495.51	2021-12-16	Buy
Sigma-Aldrich	346160	Ethynylmagnesium chloride solution 0.5 M in THF	800ml	$243	2024-03-01	Buy
Sigma-Aldrich	346160	Ethynylmagnesium chloride solution 0.5 M in THF	100ml	$75.3	2024-03-01	Buy

Properties

Density :0.921 g/mL at 25 °C
Flash point :−17 °F
storage temp. :2-8°C
form :Liquid
color :Clear brown to dark brown

Symbol(GHS):

Signal word:

Danger

Hazard statements:

Code	Hazard statements	Hazard class	Category	Signal word	P-Codes
H225	Highly Flammable liquid and vapour	Flammable liquids	Category 2	Danger	P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H261	In contact with water releases flammable gas	Substances And Mixtures Which, In Contact With Water,Emit Flammable Gases	Category 2 Category 3	Danger Warning	P231+P232, P280, P370+P378,P402+P404, P501
H302	Harmful if swallowed	Acute toxicity,oral	Category 4	Warning	P264, P270, P301+P312, P330, P501
H319	Causes serious eye irritation	Serious eye damage/eye irritation	Category 2A	Warning	P264, P280, P305+P351+P338,P337+P313P
H335	May cause respiratory irritation	Specific target organ toxicity, single exposure;Respiratory tract irritation	Category 3	Warning
H351	Suspected of causing cancer	Carcinogenicity	Category 2	Warning	P201, P202, P281, P308+P313, P405,P501

Precautionary statements:

P210	Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P231+P232	Handle under inert gas. Protect from moisture.
P280	Wear protective gloves/protective clothing/eye protection/face protection.
P370+P378	In case of fire: Use … for extinction.
P402+P404	Store in a dry place. Store in a closed container.
P403+P235	Store in a well-ventilated place. Keep cool.

Ethynylmagnesium chloride solution can be used:

To synthesize 1-ethynyldeoxyribose derivatives which can further undergo Sonogashira coupling with various aryl, heteroaryl, and metallocenyl derivatives.
In one of the key synthetic steps of substituted naphthostyrils.
In the preparation of propargylic ester precursor for the synthesis of 1,3-dienylphosphonates.

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