Diphenylsilane
- $10 - $700
- Product name: Diphenylsilane
- CAS: 775-12-2
- MF: C12H12Si
- MW: 184.31
- EINECS:212-271-4
- MDL Number:MFCD00003002
- Synonyms:DIPHENYLSILANE FOR SYNTHESIS 25 ML;DIPHENYLSILANE FOR SYNTHESIS 5 ML;Diphenylsilane, min. 97%;Diphenylsilane,97%;Diphenylsilane,99%;diphenyl-silan ;Silane,diphenyl- ;TSL8224
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Brand
- AK Scientific
- Alfa Aesar
- Alichem
- Ambeed
- Biosynth Carbosynth
- Chemenu
- Chem-Impex
- Crysdot
- Matrix Scientific
- Oakwood
- Sigma-Aldrich
- Strem Chemicals
- TCI Chemical
- TRC
- Usbiological
Package
- 100mg
- 1g
- 5g
- 10g
- 25g
- 50g
- 100g
- 250G
- 500g
- ManufacturerAK Scientific
- Product numberJ52773
- Product descriptionDiphenylsilane
- Packaging500g
- Price$695
- Updated2021-12-16
- Buy
- ManufacturerAK Scientific
- Product numberJ52773
- Product descriptionDiphenylsilane
- Packaging100g
- Price$145
- Updated2021-12-16
- Buy
- ManufacturerAK Scientific
- Product numberZ2004
- Product descriptionDiphenylsilane
- Packaging5g
- Price$26
- Updated2021-12-16
- Buy
- ManufacturerAlfa Aesar
- Product numberA10884
- Product descriptionDiphenylsilane, 97%
- Packaging5g
- Price$37.4
- Updated2024-03-01
- Buy
- ManufacturerAlfa Aesar
- Product numberA10884
- Product descriptionDiphenylsilane, 97%
- Packaging25g
- Price$117
- Updated2024-03-01
- Buy
- ManufacturerAlfa Aesar
- Product numberA10884
- Product descriptionDiphenylsilane, 97%
- Packaging100g
- Price$428
- Updated2024-03-01
- Buy
- ManufacturerAlichem
- Product number775122
- Product descriptionDiphenylsilane
- Packaging100g
- Price$285.6
- Updated2021-12-16
- Buy
- ManufacturerAmbeed
- Product numberA273991
- Product descriptionDiphenylsilane 98%
- Packaging5g
- Price$20
- Updated2021-12-16
- Buy
- ManufacturerAmbeed
- Product numberA273991
- Product descriptionDiphenylsilane 98%
- Packaging10g
- Price$32
- Updated2021-12-16
- Buy
- ManufacturerAmbeed
- Product numberA273991
- Product descriptionDiphenylsilane 98%
- Packaging25g
- Price$45
- Updated2021-12-16
- Buy
- ManufacturerAmbeed
- Product numberA273991
- Product descriptionDiphenylsilane 98%
- Packaging100g
- Price$165
- Updated2021-12-16
- Buy
- ManufacturerAmbeed
- Product numberA273991
- Product descriptionDiphenylsilane 98%
- Packaging500g
- Price$700
- Updated2021-12-16
- Buy
- ManufacturerBiosynth Carbosynth
- Product numberFP35195
- Product descriptionDiphenylsilane
- Packaging5G
- Price$50
- Updated2021-12-16
- Buy
- ManufacturerBiosynth Carbosynth
- Product numberFP35195
- Product descriptionDiphenylsilane
- Packaging10g
- Price$80
- Updated2021-12-16
- Buy
- ManufacturerBiosynth Carbosynth
- Product numberFP35195
- Product descriptionDiphenylsilane
- Packaging25g
- Price$150
- Updated2021-12-16
- Buy
- ManufacturerBiosynth Carbosynth
- Product numberFP35195
- Product descriptionDiphenylsilane
- Packaging50g
- Price$240
- Updated2021-12-16
- Buy
Manufacturer | Product number | Product description | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|
AK Scientific | J52773 | Diphenylsilane | 500g | $695 | 2021-12-16 | Buy |
AK Scientific | J52773 | Diphenylsilane | 100g | $145 | 2021-12-16 | Buy |
AK Scientific | Z2004 | Diphenylsilane | 5g | $26 | 2021-12-16 | Buy |
Alfa Aesar | A10884 | Diphenylsilane, 97% | 5g | $37.4 | 2024-03-01 | Buy |
Alfa Aesar | A10884 | Diphenylsilane, 97% | 25g | $117 | 2024-03-01 | Buy |
Alfa Aesar | A10884 | Diphenylsilane, 97% | 100g | $428 | 2024-03-01 | Buy |
Alichem | 775122 | Diphenylsilane | 100g | $285.6 | 2021-12-16 | Buy |
Ambeed | A273991 | Diphenylsilane 98% | 5g | $20 | 2021-12-16 | Buy |
Ambeed | A273991 | Diphenylsilane 98% | 10g | $32 | 2021-12-16 | Buy |
Ambeed | A273991 | Diphenylsilane 98% | 25g | $45 | 2021-12-16 | Buy |
Ambeed | A273991 | Diphenylsilane 98% | 100g | $165 | 2021-12-16 | Buy |
Ambeed | A273991 | Diphenylsilane 98% | 500g | $700 | 2021-12-16 | Buy |
Biosynth Carbosynth | FP35195 | Diphenylsilane | 5G | $50 | 2021-12-16 | Buy |
Biosynth Carbosynth | FP35195 | Diphenylsilane | 10g | $80 | 2021-12-16 | Buy |
Biosynth Carbosynth | FP35195 | Diphenylsilane | 25g | $150 | 2021-12-16 | Buy |
Biosynth Carbosynth | FP35195 | Diphenylsilane | 50g | $240 | 2021-12-16 | Buy |
Properties
Melting point :<20°C
Boiling point :95-97 °C/13 mmHg (lit.)
Density :0.993 g/mL at 25 °C (lit.)
refractive index :n20/D 1.579(lit.)
Flash point :209 °F
storage temp. :Inert atmosphere,2-8°C
form :liquid
Specific Gravity :1
color :colorless
Water Solubility :Decomposes in water.
Sensitive :Air & Moisture Sensitive
Hydrolytic Sensitivity :3: reacts with aqueous base
BRN :2935887
InChIKey :VDCSGNNYCFPWFK-UHFFFAOYSA-N
CAS DataBase Reference :775-12-2(CAS DataBase Reference)
NIST Chemistry Reference :Silane, diphenyl-(775-12-2)
EPA Substance Registry System :Silane, diphenyl- (775-12-2)
Boiling point :95-97 °C/13 mmHg (lit.)
Density :0.993 g/mL at 25 °C (lit.)
refractive index :n
Flash point :209 °F
storage temp. :Inert atmosphere,2-8°C
form :liquid
Specific Gravity :1
color :colorless
Water Solubility :Decomposes in water.
Sensitive :Air & Moisture Sensitive
Hydrolytic Sensitivity :3: reacts with aqueous base
BRN :2935887
InChIKey :VDCSGNNYCFPWFK-UHFFFAOYSA-N
CAS DataBase Reference :775-12-2(CAS DataBase Reference)
NIST Chemistry Reference :Silane, diphenyl-(775-12-2)
EPA Substance Registry System :Silane, diphenyl- (775-12-2)
Safety Information
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Signal word: | Warning | |||||||||||||||||||||
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Description
Thiocarbonyl derivatives of secondary alcohols are readily reduced by diphenylsilane in a radical chain process at room temperature using triethylborane-air as an initiator. An improved radical chain procedure for the deoxygenation of secondary and primary alcohols using diphenylsilane as hydrogen atom donor and triethylborane-air as initiator. Diphenylsilane is a reagent in the invention of radical reactions for deoxygenation of alcohols via their thiocarbonyl derivatives, deamination via isonitriles, and dehalogenation of bromo- and iodo- compounds by radical chain chemistry. Fluorescent film sensor for vapor-phase nitroaromatic explosives via monolayer assembly of oligo(diphenylsilane) on glass plate surfaces. Reductions of carboxylic acid derivatives by silanes in the presence of rhodium complexes were studied. Carboxylic esters were reduced to alcohols by diphenylsilane catalyzed by [RhCl (cod)] 2/4PPh 3 or [RhCl (PPh 3) 3] at room temperature in up to 99% yields. Sequential C- Si bond formations from diphenylsilane and its application to silanediol peptide isostere precursors.More related product prices
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