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ChemicalBook >> CAS DataBase List >> Cyclopropanecarboxaldehyde

Cyclopropanecarboxaldehyde

Cyclopropanecarboxaldehyde price.
  • $6 - $1005.43
  • Product name: Cyclopropanecarboxaldehyde
  • CAS: 1489-69-6
  • MF: C4H6O
  • MW: 70.09
  • EINECS:620-777-5
  • MDL Number:MFCD00012261
  • Synonyms:CYCLOPROPANECARBOXALDEHYDE;RARECHEM AK ML 0578;Cyclopropanecarboxyldehyde;Cyclopropanecarboxaldehyde ,98%;Cyclopropanecarboxaldehyde, 98% 5GR;Cyclopropanecarboxal;Cyclopropanecarboxaldehyde 98%;Cyclopropanecarboxaldehyde >
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  • Acrotein
  • AK Scientific
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  • Ambeed
  • American Custom Chemicals Corporation
  • Apolloscientific
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  • Frontier Specialty Chemicals
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  • TCI Chemical
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  • 250mgs:
  • ManufacturerAcrotein
  • Product numberAC-6402
  • Product descriptionCyclopropanecarboxaldehyde 97%
  • Packaging250g
  • Price$476.67
  • Updated2021-12-16
  • Buy
  • ManufacturerAK Scientific
  • Product numberJ97962
  • Product descriptionCyclopropanecarboxaldehyde
  • Packaging25g
  • Price$65
  • Updated2021-12-16
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberL14931
  • Product descriptionCyclopropanecarboxaldehyde, 98%
  • Packaging1g
  • Price$36.65
  • Updated2024-03-01
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberL14931
  • Product descriptionCyclopropanecarboxaldehyde, 98%
  • Packaging5g
  • Price$118.65
  • Updated2024-03-01
  • Buy
  • ManufacturerAmbeed
  • Product numberA520904
  • Product descriptionCyclopropanecarbaldehyde 98%
  • Packaging1g
  • Price$6
  • Updated2021-12-16
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  • ManufacturerAmbeed
  • Product numberA520904
  • Product descriptionCyclopropanecarbaldehyde 98%
  • Packaging5g
  • Price$16
  • Updated2021-12-16
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  • ManufacturerAmbeed
  • Product numberA520904
  • Product descriptionCyclopropanecarbaldehyde 98%
  • Packaging10g
  • Price$29
  • Updated2021-12-16
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  • ManufacturerAmbeed
  • Product numberA520904
  • Product descriptionCyclopropanecarbaldehyde 98%
  • Packaging25g
  • Price$56
  • Updated2021-12-16
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  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberCHM0029049
  • Product descriptionCYCLOPROPANE CARBOXALDEHYDE 95.00%
  • Packaging1G
  • Price$648.81
  • Updated2021-12-16
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  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberCHM0029049
  • Product descriptionCYCLOPROPANE CARBOXALDEHYDE 95.00%
  • Packaging2.5G
  • Price$852.21
  • Updated2021-12-16
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  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberCHM0029049
  • Product descriptionCYCLOPROPANE CARBOXALDEHYDE 95.00%
  • Packaging5G
  • Price$1005.43
  • Updated2021-12-16
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  • ManufacturerApolloscientific
  • Product numberOR52083
  • Product descriptionCyclopropanecarboxaldehyde 98%
  • Packaging25g
  • Price$73
  • Updated2021-12-16
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  • ManufacturerAtlantic Research Chemicals
  • Product numberAH09904
  • Product descriptionCyclopropanecarbaldehyde 95%
  • Packaging250mgs:
  • Price$14.14
  • Updated2021-12-16
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  • ManufacturerBiosynth Carbosynth
  • Product numberFC12072
  • Product descriptionCyclopropanecarboxaldehyde
  • Packaging5G
  • Price$90
  • Updated2021-12-16
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  • ManufacturerBiosynth Carbosynth
  • Product numberFC12072
  • Product descriptionCyclopropanecarboxaldehyde
  • Packaging10g
  • Price$130
  • Updated2021-12-16
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  • ManufacturerBiosynth Carbosynth
  • Product numberFC12072
  • Product descriptionCyclopropanecarboxaldehyde
  • Packaging25g
  • Price$200
  • Updated2021-12-16
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Acrotein AC-6402 Cyclopropanecarboxaldehyde 97% 250g $476.67 2021-12-16 Buy
AK Scientific J97962 Cyclopropanecarboxaldehyde 25g $65 2021-12-16 Buy
Alfa Aesar L14931 Cyclopropanecarboxaldehyde, 98% 1g $36.65 2024-03-01 Buy
Alfa Aesar L14931 Cyclopropanecarboxaldehyde, 98% 5g $118.65 2024-03-01 Buy
Ambeed A520904 Cyclopropanecarbaldehyde 98% 1g $6 2021-12-16 Buy
Ambeed A520904 Cyclopropanecarbaldehyde 98% 5g $16 2021-12-16 Buy
Ambeed A520904 Cyclopropanecarbaldehyde 98% 10g $29 2021-12-16 Buy
Ambeed A520904 Cyclopropanecarbaldehyde 98% 25g $56 2021-12-16 Buy
American Custom Chemicals Corporation CHM0029049 CYCLOPROPANE CARBOXALDEHYDE 95.00% 1G $648.81 2021-12-16 Buy
American Custom Chemicals Corporation CHM0029049 CYCLOPROPANE CARBOXALDEHYDE 95.00% 2.5G $852.21 2021-12-16 Buy
American Custom Chemicals Corporation CHM0029049 CYCLOPROPANE CARBOXALDEHYDE 95.00% 5G $1005.43 2021-12-16 Buy
Apolloscientific OR52083 Cyclopropanecarboxaldehyde 98% 25g $73 2021-12-16 Buy
Atlantic Research Chemicals AH09904 Cyclopropanecarbaldehyde 95% 250mgs: $14.14 2021-12-16 Buy
Biosynth Carbosynth FC12072 Cyclopropanecarboxaldehyde 5G $90 2021-12-16 Buy
Biosynth Carbosynth FC12072 Cyclopropanecarboxaldehyde 10g $130 2021-12-16 Buy
Biosynth Carbosynth FC12072 Cyclopropanecarboxaldehyde 25g $200 2021-12-16 Buy

Properties

Boiling point :98-101 °C (lit.)
Density :0.938 g/mL at 25 °C (lit.)
refractive index :n20/D 1.4298(lit.)
Flash point :45 °F
storage temp. :2-8°C
solubility :soluble in Chloroform
form :clear liquid
color :Colorless to Light orange to Yellow
Water Solubility :Soluble in water.
Sensitive :Air Sensitive
BRN :906781
Stability :Volatile
InChIKey :JMYVMOUINOAAPA-UHFFFAOYSA-N
CAS DataBase Reference :1489-69-6(CAS DataBase Reference)
NIST Chemistry Reference :Cyclopropanecarboxaldehyde(1489-69-6)
EPA Substance Registry System :Cyclopropanecarboxaldehyde (1489-69-6)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H225 Highly Flammable liquid and vapour Flammable liquids Category 2 Danger GHS hazard pictograms P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P233 Keep container tightly closed.
P240 Ground/bond container and receiving equipment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

Cyclopropanecarboxaldehyde reacts with Grignard or organolithium reagents to give the expected secondary alcohols. These are susceptible to ring opening in the presence of HBr, providing stereoselective access to homoallylic bromides. It is also used in the synthesis of eta(2)-enonenickel complexes by reacting with [Ni(cod)(2)] (cod = 1,5-cyclooctadiene) and PBu(3) and to prepare a cyclopropylidene tetralone which underwent an enantioselective palladium-catalyzed [3+2] TMM cycloaddition providing a chiral spiro-fused cyclopentene.

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