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ChemicalBook >> CAS DataBase List >> tert-Butyl (2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate

tert-Butyl (2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate

tert-Butyl (2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate price.
  • $21 - $1739.43
  • Product name: tert-Butyl (2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate
  • CAS: 112741-50-1
  • MF: C21H23NO4
  • MW: 353.41
  • EINECS:627-150-5
  • MDL Number:MFCD00074953
  • Synonyms:(2S,3R)-6-Oxo-2,3-diphenyl-morpholine-4-carboxylic acid tert-butyl ester;(5S,6R)-(+)-4-Boc-5,6-diphenyl-2-Morpholinone, 99%;(2S,3R)-(+)-N-Boc-6-oxo-2,3-diphenylMorpholine;(5R,6S)-N-Boc-5,6-diphenyl-2-morpholinone;tert-butyl (2S,3R)-6-oxo-2,3-diphenylMorpholine-4-carboxylate;(2S,3R)-(+)-N-Boc-6-oxo-2,3-diphenylMorpholine;(2S, 3R) - (+) - N- t-butoxycarbonyl-6-oxo-2,3-diphenyl-Morpholine;(2S,3R)-6-Oxo-2,3-diphenyl-4-morpholinecarboxylic Acid 1,1-Dimethylethyl Ester
28 prices
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  • Abosyn
  • AK Scientific
  • Alichem
  • Ambeed
  • American Custom Chemicals Corporation
  • Biosynth Carbosynth
  • Chemenu
  • Chem-Impex
  • Crysdot
  • Matrix Scientific
  • Sigma-Aldrich
  • TRC
Package
  • 250mg
  • 500mg
  • 1g
  • 2g
  • 2.5g
  • 5g
  • 10g
  • 25g
  • ManufacturerAbosyn
  • Product number61-1049
  • Product description(2S,3R)-tert-butyl6-oxo-2,3-diphenylmorpholine-4-carboxylate 95-98%
  • Packaging1g
  • Price$400
  • Updated2021-12-16
  • Buy
  • ManufacturerAK Scientific
  • Product numberX9028
  • Product descriptionN-Boc-(2S,3R)-(+)-6-Oxo-2,3-diphenyl-4-morpholinecarboxylate
  • Packaging25g
  • Price$852
  • Updated2021-12-16
  • Buy
  • ManufacturerAlichem
  • Product number112741501
  • Product descriptiontert-Butyl(2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate
  • Packaging10g
  • Price$285.32
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA488941
  • Product description(2S,3R)-tert-Butyl6-oxo-2,3-diphenylmorpholine-4-carboxylate 95+%
  • Packaging250mg
  • Price$21
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA488941
  • Product description(2S,3R)-tert-Butyl6-oxo-2,3-diphenylmorpholine-4-carboxylate 95+%
  • Packaging1g
  • Price$47
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA488941
  • Product description(2S,3R)-tert-Butyl6-oxo-2,3-diphenylmorpholine-4-carboxylate 95+%
  • Packaging5g
  • Price$135
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA488941
  • Product description(2S,3R)-tert-Butyl6-oxo-2,3-diphenylmorpholine-4-carboxylate 95+%
  • Packaging10g
  • Price$226
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA488941
  • Product description(2S,3R)-tert-Butyl6-oxo-2,3-diphenylmorpholine-4-carboxylate 95+%
  • Packaging25g
  • Price$495
  • Updated2021-12-16
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  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberCHM0014687
  • Product descriptionN-BOC(2S, 3R)-(+)-6-OXO-2,3-DIPHENYL-4-MORPHOLINE CARBOXYLATE 95.00%
  • Packaging1G
  • Price$958.65
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberCHM0014687
  • Product descriptionN-BOC(2S, 3R)-(+)-6-OXO-2,3-DIPHENYL-4-MORPHOLINE CARBOXYLATE 95.00%
  • Packaging5G
  • Price$1739.43
  • Updated2021-12-16
  • Buy
  • ManufacturerBiosynth Carbosynth
  • Product numberFB63306
  • Product description(2S,3R)-tert-Butyl 6-oxo-2,3-diphenylmorpholine-4-carboxylate
  • Packaging500mg
  • Price$190
  • Updated2021-12-16
  • Buy
  • ManufacturerBiosynth Carbosynth
  • Product numberFB63306
  • Product description(2S,3R)-tert-Butyl 6-oxo-2,3-diphenylmorpholine-4-carboxylate
  • Packaging1g
  • Price$300
  • Updated2021-12-16
  • Buy
  • ManufacturerBiosynth Carbosynth
  • Product numberFB63306
  • Product description(2S,3R)-tert-Butyl 6-oxo-2,3-diphenylmorpholine-4-carboxylate
  • Packaging2g
  • Price$480
  • Updated2021-12-16
  • Buy
  • ManufacturerBiosynth Carbosynth
  • Product numberFB63306
  • Product description(2S,3R)-tert-Butyl 6-oxo-2,3-diphenylmorpholine-4-carboxylate
  • Packaging5G
  • Price$825
  • Updated2021-12-16
  • Buy
  • ManufacturerBiosynth Carbosynth
  • Product numberFB63306
  • Product description(2S,3R)-tert-Butyl 6-oxo-2,3-diphenylmorpholine-4-carboxylate
  • Packaging10g
  • Price$1105
  • Updated2021-12-16
  • Buy
  • ManufacturerChemenu
  • Product numberCM105764
  • Product descriptiontert-butyl(2S,3R)-6-oxo-2,3-diphenylMorpholine-4-carboxylate 95%
  • Packaging5g
  • Price$184
  • Updated2021-12-16
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Abosyn 61-1049 (2S,3R)-tert-butyl6-oxo-2,3-diphenylmorpholine-4-carboxylate 95-98% 1g $400 2021-12-16 Buy
AK Scientific X9028 N-Boc-(2S,3R)-(+)-6-Oxo-2,3-diphenyl-4-morpholinecarboxylate 25g $852 2021-12-16 Buy
Alichem 112741501 tert-Butyl(2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate 10g $285.32 2021-12-16 Buy
Ambeed A488941 (2S,3R)-tert-Butyl6-oxo-2,3-diphenylmorpholine-4-carboxylate 95+% 250mg $21 2021-12-16 Buy
Ambeed A488941 (2S,3R)-tert-Butyl6-oxo-2,3-diphenylmorpholine-4-carboxylate 95+% 1g $47 2021-12-16 Buy
Ambeed A488941 (2S,3R)-tert-Butyl6-oxo-2,3-diphenylmorpholine-4-carboxylate 95+% 5g $135 2021-12-16 Buy
Ambeed A488941 (2S,3R)-tert-Butyl6-oxo-2,3-diphenylmorpholine-4-carboxylate 95+% 10g $226 2021-12-16 Buy
Ambeed A488941 (2S,3R)-tert-Butyl6-oxo-2,3-diphenylmorpholine-4-carboxylate 95+% 25g $495 2021-12-16 Buy
American Custom Chemicals Corporation CHM0014687 N-BOC(2S, 3R)-(+)-6-OXO-2,3-DIPHENYL-4-MORPHOLINE CARBOXYLATE 95.00% 1G $958.65 2021-12-16 Buy
American Custom Chemicals Corporation CHM0014687 N-BOC(2S, 3R)-(+)-6-OXO-2,3-DIPHENYL-4-MORPHOLINE CARBOXYLATE 95.00% 5G $1739.43 2021-12-16 Buy
Biosynth Carbosynth FB63306 (2S,3R)-tert-Butyl 6-oxo-2,3-diphenylmorpholine-4-carboxylate 500mg $190 2021-12-16 Buy
Biosynth Carbosynth FB63306 (2S,3R)-tert-Butyl 6-oxo-2,3-diphenylmorpholine-4-carboxylate 1g $300 2021-12-16 Buy
Biosynth Carbosynth FB63306 (2S,3R)-tert-Butyl 6-oxo-2,3-diphenylmorpholine-4-carboxylate 2g $480 2021-12-16 Buy
Biosynth Carbosynth FB63306 (2S,3R)-tert-Butyl 6-oxo-2,3-diphenylmorpholine-4-carboxylate 5G $825 2021-12-16 Buy
Biosynth Carbosynth FB63306 (2S,3R)-tert-Butyl 6-oxo-2,3-diphenylmorpholine-4-carboxylate 10g $1105 2021-12-16 Buy
Chemenu CM105764 tert-butyl(2S,3R)-6-oxo-2,3-diphenylMorpholine-4-carboxylate 95% 5g $184 2021-12-16 Buy

Properties

Melting point :206 °C (dec.)(lit.)
Boiling point :509.6±50.0 °C(Predicted)
alpha :86 º (c=5.5 in methylene chloride)
Density :1.175±0.06 g/cm3(Predicted)
storage temp. :2-8°C
pka :-3.28±0.60(Predicted)
optical activity :[α]20/D +86°, c = 5.5 in methylene chloride
InChIKey :MRUKRSQUUNYOFK-MOPGFXCFSA-N
CAS DataBase Reference :112741-50-1(CAS DataBase Reference)

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

(2S,3R)-(+)-N-Boc-6-oxo-2,3-diphenylmorpholine (Williams chiral auxiliary) can be used as a reactant:
  • In the asymmetric synthesis of cylindrospermopsin and related alkaloids via an intramolecular 1,3-dipolar cycloaddition reaction.
  • To synthesize boc-3-(1-methylcyclopropyl)-D-alanine, which is used as an intermediate to prepare 4-fluoroproline-based analogs as potent tripeptide thrombin inhibitors.
  • In the total synthesis of potent hepatotoxic alkaloid 7-epicylindrospermopsin by intramolecular 1,3-dipolar cycloaddition and nitroaldol reaction.
  • To prepare differentially functionalized diaminoglutamic acids via radical reaction of selenide with methyl 2-acetamidoacrylate.

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