1,3-Butanediol
Product identifier
- Product name: 1,3-Butanediol
- CBnumber: CB7758265
- CAS: 107-88-0
- EINECS Number: 203-529-7
- Synonyms: 1,3-Butanediol,BD
Relevant identified uses of the substance or mixture and uses advised against
- Relevant identified uses: For R&D use only. Not for medicinal, household or other use.
- Uses advised against: none
Company Identification
- Company: Chemicalbook
- Address: Building 1, Huihuang International, Shangdi 10th Street, Haidian District, Beijing
- Telephone: 400-158-6606
GHS Label elements, including precautionary statements
-
Symbol(GHS)
- Signal wordWarning
Substance
- Product name: 1,3-Butanediol
- Synonyms: 1,3-Butanediol,BD
- CAS: 107-88-0
- EC number: 203-529-7
- MF: C4H10O2
- MW: 90.12
Description of first aid measures
General adviceMost important symptoms and effects, both acute and delayed
Indication of any immediate medical attention and special treatment needed
Extinguishing media
Suitable extinguishing mediaSpecial hazards arising from the substance or mixture
Nature of decomposition products not known. Combustible.
Vapors are heavier than air and may spread along floors. Forms explosive mixtures with air on intense heating.
Development of hazardous combustion gases or vapours possible in the event of fire.
Advice for firefighters
In the event of fire, wear self-contained breathing apparatus.
Further information
Prevent fire extinguishing water from contaminating surface water or the ground water system.
NFPA 704
| HEALTH | 1 | Exposure would cause irritation with only minor residual injury (e.g. acetone, sodium bromate, potassium chloride) | |
| FIRE | 1 | Materials that require considerable preheating, under all ambient temperature conditions, before ignition and combustion can occur. Includes some finely divided suspended solids that do not require heating before ignition can occur. Flash point at or above 93.3 °C (200 °F). (e.g. mineral oil, ammonia) | |
| REACT | 0 | Normally stable, even under fire exposure conditions, and is not reactive with water (e.g. helium,N2) | |
| SPEC. HAZ. |
Personal precautions, protective equipment and emergency procedures
Advice for non-emergency personnel: Do not breathe vapors, aerosols. Avoid substance contact. Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures, consult an expert.
For personal protection see section 8.
Environmental precautions
Do not let product enter drains.
Methods and materials for containment and cleaning up
Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up with liquid-absorbent material (e.g. Chemizorb? ). Dispose of properly. Clean up affected area.
Reference to other sections
For disposal see section 13.
Precautions for safe handling
For precautions see section 2.2.
Conditions for safe storage, including any incompatibilities
Tightly closed.
hygroscopic
Specific end use(s)
Apart from the uses mentioned in section 1.2 no other specific uses are stipulated
control parameter
Hazard composition and occupational exposure limitsExposure controls
Appropriate engineering controlsChange contaminated clothing. Wash hands after working with substance.
Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Safety glasses
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands.
The selected protective gloves have to satisfy the specifications of Regulation (EU) 2016/425 and the standard EN 374 derived from it.
Full contact
Material: Nitrile rubber
Minimum layer thickness: 0,11 mm Break through time: 480 min
Material tested:Dermatril? (KCL 740 / Aldrich Z677272, Size M)
Splash contact Material: Nitrile rubber
Minimum layer thickness: 0,11 mm Break through time: 480 min
Material tested:Dermatril? (KCL 740 / Aldrich Z677272, Size M)
data source: KCL GmbH, D-36124 Eichenzell, phone +49 (0)6659 87300, e-mail sales@kcl.de, test method: EN374
If used in solution, or mixed with other substances, and under conditions which differ from EN 374, contact the supplier of the EC approved gloves. This recommendation is advisory only and must be evaluated by an industrial hygienist and safety officer familiar with the specific situation of anticipated use by our customers. It should not be construed as offering an approval for any specific use scenario.
protective clothing
required when vapours/aerosols are generated.
Our recommendations on filtering respiratory protection are based on the following standards: DIN EN 143, DIN 14387 and other accompanying standards relating to the used respiratory protection system.
Do not let product enter drains.
Information on basic physicochemical properties
- Appearancecolorless, clear liquid
- Odourodorless
- Odour ThresholdNo data available d) pH 6,0 - 7,0 at 20 °C Melting point/freezing point Initial boiling point and boiling range Melting point/freezing point: -57 °C - ISO 3016 203 - 204 °C - lit. Flash point 108 °C - closed cup Evaporation rate No data available Flammability (solid, gas) Upper/lower flammability or explosive limits No data available Upper explosion limit: 12,6 %(V) Lower explosion limit: 1,9 %(V) Vapour pressure 0,08 hPa at 20 °C Vapour density 3,11 - (Air = 1.0) Relative density 1,005 g/cm3 at 25 °C Water solubility 500 g/l at 20 °C - OECD Test Guideline 105 - miscible Partition coefficient: n-octanol/water Autoignition temperature Decomposition temperature log Pow: -0,9 at 25 °C - Bioaccumulation is not expected. 410 °C at 1.019 hPa - DIN 51794 No data available Viscosity No data available Explosive properties No data available Oxidizing properties No data available
- Melting point/freezing pointMelting point/freezing point: -57 °C - ISO 3016
- Initial boiling point and boiling range 203 - 204 °C - lit.
- Flash point108 °C - closed cup
- Evaporation rate250 °F
- Flammability (solid, gas)No data available
- Upper/lower flammability or explosive limits Upper explosion limit: 12,6 %(V) Lower explosion limit: 1,9 %(V)
- Vapour pressure 0,08 hPa at 20 °C
- Vapour density 3,11 - (Air = 1.0)
- Relative density1,005 g/cm3 at 25 °C
- Water solubility500 g/l at 20 °C - OECD Test Guideline 105 - miscible
- Partition coefficient: n-octanol/waterlog Pow: -0,9 at 25 °C - Bioaccumulation is not expected.
- Autoignition temperature410 °C at 1.019 hPa - DIN 51794
- Decomposition temperature No data available
- ViscosityNo data available
- Explosive propertiesNo data available
- Oxidizing propertiesNo data available
Other safety information
Surface tension 72,6 mN/m at 1g/l at 20 °C
-
OECD Test Guideline 115
Dissociation constant 15,5 at 25 °C
-
OECD Test Guideline 112
Relative vapor density
3,11 - (Air = 1.0)
Reactivity
Forms explosive mixtures with air on intense heating.
A range from approx. 15 Kelvin below the flash point is to be rated as critical.
Chemical stability
The product is chemically stable under standard ambient conditions (room temperature) .
Possibility of hazardous reactions
No data available
Conditions to avoid
Incompatible materials
Strong oxidizing agents, Acid chlorides, Acid anhydrides, Chloroformates, Reducing agents
Hazardous decomposition products
Other decomposition products - No data available
Hazardous decomposition products formed under fire conditions. - Nature of decomposition products not known.
In the event of fire: see section 5
Information on toxicological effects
Acute toxicityRemarks: (ECHA)
LD50 Dermal - Rabbit - > 20.000 mg/kg Remarks: (RTECS)
Result: Mild skin irritation - 24 h Remarks: (RTECS)
Result: Irritation to eyes, reversing within 7 days - 18 h Remarks: (ECHA)
Escherichia coli/Salmonella typhimurium Result: negative
Rat - male and female - Bone marrow Result: negative
(ECHA)
Rat - male and female Result: negative (ECHA)
To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.
Hazardous properties cannot be excluded but are unlikely when the product is handled appropriately.
Handle in accordance with good industrial hygiene and safety practice.
Toxicity
(OECD Test Guideline 203)
static test EC50 - Daphnia magna (Water flea) - > 1.000 mg/l - 48 h (OECD Test Guideline 202)
1.070 mg/l - 72 h
(OECD Test Guideline 201)
Persistence and degradability
Biodegradability aerobic - Exposure time 29 d
Result: 81 % - Readily biodegradable.
(OECD Test Guideline 301B)
Bioaccumulative potential
No data available
Mobility in soil
No data available
Results of PBT and vPvB assessment
This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
Other adverse effects
No data available
Waste treatment methods
Product
See www.retrologistik.com for processes regarding the return of chemicals and
containers, or contact us there if you have further questions.
IncompatibilitiesButylene glycol is incompatible with oxidizing reagents.
UN number
ADR/RID: - IMDG: - IATA: -
UN proper shipping name
Transport hazard class(es)
ADR/RID: - IMDG: - IATA: -
Packaging group
ADR/RID: - IMDG: - IATA: -
Environmental hazards
ADR/RID: no IMDG Marine pollutant: no IATA: no
Special precautions for user
Further information
Not classified as dangerous in the meaning of transport regulations.
Safety, health and environmental regulations/legislation specific for the substance or mixture
Regulations on the Safety Management of Hazardous ChemicalsAbbreviations and acronyms
- CAS: Chemical Abstracts Service
- ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
- RID: Regulation concerning the International Carriage of Dangerous Goods by Rail
- IMDG: International Maritime Dangerous Goods
- IATA: International Air Transportation Association
- TWA: Time Weighted Average
- STEL: Short term exposure limit
- LC50: Lethal Concentration 50%
- LD50: Lethal Dose 50%
- EC50: Effective Concentration 50%
References
【1】CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple
【2】ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp
【3】ECHA - European Chemicals Agency, website: https://echa.europa.eu/
【4】eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en
【5】ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg
【6】Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp
【7】HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm
【8】IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/
【9】IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home
【10】Sigma-Aldrich, website: https://www.sigmaaldrich.com/
The information in this MSDS is only applicable to the specified product, unless otherwise specified, it is not applicable to the mixture of this product and other substances. This MSDS only provides information on the safety of the product for those who have received the appropriate professional training for the user of the product. Users of this MSDS must make independent judgments on the applicability of this SDS. The authors of this MSDS will not be held responsible for any harm caused by the use of this MSDS.