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Angewandte Chemie International Edition

Angewandte Chemie International Edition

IF: 16.1
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The Solid-State Structures of Dimethylzinc and Diethylzinc

Published:14 September 2011 DOI: 10.1002/anie.201105099 PMID: 21919175
Dr. John Bacsa, Dr. Felix Hanke, Sarah Hindley, Dr. Rajesh Odedra, Dr. George R. Darling, Prof. Anthony C. Jones, Dr. Alexander Steiner

Abstract

Good things come to those who wait: More than 160 years after their discovery, we have determined the solid-state structures of the classic organometallic compounds dimethylzinc and diethylzinc by using X-ray crystallography and density functional theory. The study shows that the linear molecules form weak intermolecular interactions with small covalent contributions. Me2Zn undergoes a solid–solid phase transition at 180?K (see picture).

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