對(duì)叔丁基芐硫醇中文同義詞對(duì)叔丁基芐硫醇;[4-(叔丁基)苯基]甲硫醇;PERFEMIKER]對(duì)叔丁基芐硫醇,97%英文名稱4-(tert-Butyl)benzylmercaptan英文同義詞4-tert-Butylbenzylthiol;4-TERT-BUTYLBENZYLMERCAPTAN;[4-(TERT-BUTYL)PHENYL]METHANETHIOL;4-tert-Butylbenzylmercaptane;4-(1,1-DIMETHYLETHYL)BENZENEMETHANETHIOL;P-TERT-BUTYLBENZYLTHIOL;4-tert-Butylbenzenemethanethiol;tert-ButylbenzylMercaptCAS號(hào)49543-63-7分子式C11H16S分子量180.31EINECS號(hào)相關(guān)類別農(nóng)藥中間體;殺螨劑中間體;有機(jī)砌塊;醫(yī)藥中間體;硫醇類;巰基化合物;化工原料;有機(jī)化工原料;OrganicBuildingBlocks;SulfurCompounds;Thiols/MercaptansMol文件49543-63-7.mol結(jié)構(gòu)式對(duì)叔丁基芐硫醇性質(zhì)沸點(diǎn)102-103°C3.1mmHg(lit.)密度0.966g/mLat25°C(lit.)折射率n20/D1.5430(lit.)閃點(diǎn)162°F酸度系數(shù)(pKa)9.83±0.10(Predicted)形態(tài)透明液體顏色無(wú)色至淺黃色至淺橙色CAS數(shù)據(jù)庫(kù)49543-63-7(CASDataBaseReference)對(duì)叔丁基芐硫醇用途與合成方法用途對(duì)叔丁基芐硫醇是合成殺螨劑噠螨靈的中間體。生產(chǎn)方法其制備方法是向容量為300mL的四口反應(yīng)燒瓶?jī)?nèi)，加入對(duì)叔丁基芐氯18.3g(0.1mol)、甲苯100g、四丁基溴化銨0.5g和乙酸1.8g(0.03mol)，加熱升溫至50℃后，在攪拌下滴加23％硫氫化鈉水溶液31.7g(0.13mol)。經(jīng)30min滴加完畢后，再于50℃下繼續(xù)攪拌反應(yīng)30min，將其冷卻至室溫，靜置后分層，水洗甲苯層，蒸除甲苯，濃縮即得外觀呈淡黃色液體的對(duì)叔丁基芐硫醇18.0g，純度93％，合成收率為92％。若再對(duì)其進(jìn)行精餾，收集沸程為90～92℃/532Pa的餾分，則對(duì)叔丁基芐硫醇的純度可達(dá)99％。對(duì)叔丁基芐硫醇純品為無(wú)色透明液體，有硫醇臭味，與大多數(shù)有機(jī)溶劑互溶，工業(yè)品含量95％。