2-硝基苯肼鹽酸鹽(6293-87-4)紅外圖譜(IR3)
分子式:C6H8ClN3O2
分子量: 189.6
InChI:InChI=1S/C6H7N3O2.ClH/c7-8-5-3-1-2-4-6(5)9(10)11;/h1-4,8H,7H2;1H
InChIKey: XCUBVSAYUSFHNN-UHFFFAOYSA-N
Smiles:C1(NN)=CC=CC=C1[N+]([O-])=O.Cl
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Mass
MS-IW-1885
(o-nitrophenyl)hydrazine monohydrochloride
C6H7N3O2 HCl (Mass of molecular ion: 153)
Source Temperature: 130 °C
Sample Temperature: 120 °C
Direct, 75 eV
18.0 1.4
27.0 3.2
28.0 6.5
29.0 3.0
30.0 4.3
31.0 1.0
35.0 5.6
36.0 48.1
37.0 3.8
38.0 17.0
39.0 12.8
40.0 1.9
41.0 1.9
43.0 1.0
50.0 13.4
51.0 35.7
52.0 96.3
53.0 20.7
54.0 2.5
61.0 1.9
62.0 4.2
63.0 17.0
64.0 15.5
65.0 10.0
66.0 1.8
74.0 4.1
75.0 3.8
76.0 10.4
76.5 2.9
77.0 100.0
78.0 29.7
79.0 25.0
80.0 7.3
90.0 14.9
91.0 22.4
92.0 6.7
93.0 2.2
105.0 5.4
106.0 1.6
107.0 1.8
119.0 5.0
135.0 9.6
136.0 2.4
153.0 84.2
154.0 6.6
400 MHz in DMSO-d6
90 MHz in D2O
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| 1H NMR |
399.65 MHz |
| C6 H7 N3 O2
|
saturated in DMSO-d6
|
| (o-nitrophenyl)hydrazine monohydrochloride
|
 |
Assign. Shift(ppm)
A 10.6
B 9.25
C 8.164
D 7.760
E 7.392
F 7.104
|
Hz ppm Int.
4234.44 10.596 51
3698.31 9.254 266
3268.06 8.178 941
3266.59 8.174 997
3259.63 8.157 987
3257.98 8.153 983
3110.35 7.783 444
3108.70 7.779 471
3104.86 7.769 131
3103.02 7.765 551
3101.74 7.762 881
3100.28 7.758 603
3094.60 7.744 542
3093.13 7.740 518
2958.87 7.404 878
2957.77 7.401 942
2950.26 7.383 819
2949.35 7.380 820
2847.51 7.126 544
2846.22 7.122 592
2840.18 7.107 616
2839.08 7.104 1000
2837.80 7.101 645
2831.75 7.086 526
2830.66 7.083 535
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| 1H NMR |
89.56 MHz |
| C6 H7 N3 O2
|
0.038 g : 0.5 ml D2O
|
| (o-nitrophenyl)hydrazine monohydrochloride
|
|
Assign. Shift(ppm)
A 8.243
B 7.790
C 7.23
D 7.18
THE SOLVENT SIGNAL REMOVED.
|
Hz ppm Int.
744.25 8.311 270
743.31 8.300 258
742.50 8.291 436
736.31 8.222 247
735.44 8.212 349
733.88 8.195 539
707.31 7.898 226
705.75 7.881 237
700.75 7.825 127
700.00 7.816 232
698.56 7.800 400
697.19 7.785 340
691.63 7.723 413
690.00 7.705 389
651.75 7.278 951
651.13 7.271 942
648.69 7.244 100
643.31 7.184 1000
642.00 7.169 482
636.06 7.103 273
634.81 7.089 225