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Picture of Dipheny(t-butyl)phosphine, 98%
300684

Dipheny(t-butyl)phosphine, 98%

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Products specifications
Assay 98%
CAS # 6002-34-2
MDL # MFCD00015004
Molecular Formula C16H19P
Molecular Weight 242.30
Appearance white xtl.
Melting Point 52-57 °C
Boiling Point 144-146 °C/2 mmHg
Flash Point >110 °C (>230 °F)
Vapor Pressure 0.000594 mmHg (25 °C)
Application New family of Ph2(t-Bu)P phosphines for efficient Silyl-Heck transformations.
Reference McAtee, J. R. et al. J. Am. Chem. Soc. 2014, 136, 10166; Martin, S. E. S. et al. J. Am. Chem. Soc. 2013, 135, 13330; McAtee, J. R. et al. Angew. Chem. Int. Ed. 2012, 51, 3663.
Signal WordWarning
Hazard CodesH301-H315-H319
Hazard StatementsToxic if swallowed. Causes skin irritation. Causes serious eye irritation.
Precautionary CodesP280-P301+P310-P305+P351+P338-P362-P405-P501A
Precautionary StatementsWear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Take off contaminated clothing and wash before reuse. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.
Risk Codes22-36/37/38
Risk PhrasesHarmful if swallowed. Irritating to eyes and skin.
Safety Codes26-37
Safety PhrasesIn case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing and gloves.
WGK Germany3
Personal Protective Equipmentdust mask type N95 (US), Eyeshields, Gloves
TSCANo
Products specifications
Assay 98%
CAS # 6002-34-2
MDL # MFCD00015004
Molecular Formula C16H19P
Molecular Weight 242.30
Appearance white xtl.
Melting Point 52-57 °C
Boiling Point 144-146 °C/2 mmHg
Flash Point >110 °C (>230 °F)
Vapor Pressure 0.000594 mmHg (25 °C)
Application New family of Ph2(t-Bu)P phosphines for efficient Silyl-Heck transformations.
Reference McAtee, J. R. et al. J. Am. Chem. Soc. 2014, 136, 10166; Martin, S. E. S. et al. J. Am. Chem. Soc. 2013, 135, 13330; McAtee, J. R. et al. Angew. Chem. Int. Ed. 2012, 51, 3663.