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Chemical Structure| 99646-28-3 Chemical Structure| 99646-28-3

Structure of 99646-28-3

Chemical Structure| 99646-28-3

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CAS No.: 99646-28-3

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Product Details of [ 99646-28-3 ]

CAS No. :99646-28-3
Formula : C48H40P2
M.W : 678.78
SMILES Code : CC1=CC=C(P(C2=CC=C3C=CC=CC3=C2C4=C5C=CC=CC5=CC=C4P(C6=CC=C(C)C=C6)C7=CC=C(C)C=C7)C8=CC=C(C)C=C8)C=C1
MDL No. :MFCD01311709
InChI Key :IOPQYDKQISFMJI-UHFFFAOYSA-N
Pubchem ID :4189906

Safety of [ 99646-28-3 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H317-H319
Precautionary Statements:P280-P305+P351+P338

Application In Synthesis of [ 99646-28-3 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 99646-28-3 ]

[ 99646-28-3 ] Synthesis Path-Downstream   1~3

  • 1
  • [ 12112-67-3 ]
  • [ 591-87-7 ]
  • [ 153775-42-9 ]
  • [ 99646-28-3 ]
  • [ 1613234-48-2 ]
  • 2
  • [ 12112-67-3 ]
  • [ 591-87-7 ]
  • [ 153775-42-9 ]
  • [ 99646-28-3 ]
  • [ 1613234-48-2 ]
  • 3
  • [ 64443-05-6 ]
  • [ 17217-57-1 ]
  • [ 99646-28-3 ]
  • [Cu(4,4'-dimethoxy-2,2'-bipyridine)((R)-(+)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl)]*PF6 [ No CAS ]
YieldReaction ConditionsOperation in experiment
65% In dichloromethane; at 20℃; for 1.5h; General procedure: [Cu-(MeCN)4]PF6 (74 mg, 0.20 mmol) was added to TolBINAP(135 mg, 0.20 mmol) in 2 mL CH2Cl2. Then, bpy (31 mg, 0.20mmol) was added. The yellow reaction mixture was stirred for90 minutes at room temperature. Diethyl ether (25 mL) wasadded to the solution to precipitate the product as a yellowsolid, which was filtered and dried in vacuum.
 

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[ 99646-28-3 ]

Chemical Structure| 100165-88-6

A491448 [100165-88-6]

(S)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl

Reason: Optical isomers