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Search for reports by entering the product batch number.
Batch number can be found on the product's label following the word 'Batch'.
Search for reports by entering the product batch number.
Batch number can be found on the product's label following the word 'Batch'.
Search for reports by entering the product batch number.
Batch number can be found on the product's label following the word 'Batch'.
Search for reports by entering the product batch number.
Batch number can be found on the product's label following the word 'Batch'.
Search for reports by entering the product batch number.
Batch number can be found on the product's label following the word 'Batch'.
CAS No. : | 941-98-0 |
Formula : | C12H10O |
M.W : | 170.21 |
SMILES Code : | CC(C1=C2C=CC=CC2=CC=C1)=O |
MDL No. : | MFCD00004013 |
InChI Key : | QQLIGMASAVJVON-UHFFFAOYSA-N |
Pubchem ID : | 13663 |
GHS Pictogram: |
![]() |
Signal Word: | Warning |
Hazard Statements: | H302-H315-H319-H335 |
Precautionary Statements: | P261-P305+P351+P338 |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
68% | With sodium hydroxide; In ethanol; chloroform; at 20℃; | The 816 mg (4.8mmol) α- acetonaphthone , 240 mg (6mmol) sodium hydroxide in 100 ml of water, adding 6 ml ethanol, 12 drip enable its dissolution. The 1302 mg (4.8mmol) 4-(9-(9H-carbazolyl)) benzaldehyde dissolved in 18 ml in chloroform, in the above-mentioned is dripped into the ethanol solution, stirring the mixture at room temperature for overnight, to stop the reaction. Overhanging organic solvent, water and dilute, dichloromethane extraction, drying, recrystallized (petroleum ether: ethyl acetate = 15 the [...] 1), to get the yellow cluster crystal a1.37g, yield = 68%. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
With sodium hydroxide; In ethanol; water; at 20℃; for 2h; | General procedure: An aqueous solution of sodium hydroxide (5%, 10mL) was added slowly to the stirring solution of isatin (1mmol) and appropriate aryl acetophenone (1mmol) in ethanol (20mL) in 100mL conical flask. The stirring was continued for 2h and the completion of reaction was monitored by TLC. The reaction on completion was poured onto ice, solid obtained after filtration was crystallized from ethanol. The physical data for the characteristic compound is shown below: |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
70% | With tris(triphenylphosphine)ruthenium(II) chloride; caesium carbonate; at 150℃; for 3h;Inert atmosphere; | Under an argon atmosphere, carbonylchloro hydride tris (triphenylphosphine)ruthenium 4.8 mg (5.0μmol), 2-(4- iodophenyl) -5,5 - dimethyl -1, 3, 2 - dioxaborinane 316 mg (1.00mmol), cesium carbonate 97.8mg (300μmol) and 1 - acetonaphthone 1.12 mg (6.58 mmol) are added in a reactioncontainer. The reactionvessel is heated on 135 ,and it is stirred for 12 hour. After thereaction vessel cooled as room temperature,mixture is purified by using silica gel columnchromatography (hexane : ethyl acetate = 10 : 0-9 : 1), 260 mg of 1 - [2 - (4- iodophenyl) naphthalene - 1- yl] ethanone obtained (white solid, yield 70%). |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
39% | With sodium hydroxide; In dimethyl sulfoxide; at 20℃; | General procedure: To a solution of 3,3-bis(methylsulfanyl)methylenemalononitrile 1 (1.70 g, 10 mmol) in 20 mL of DMSO, keton 2a - j (10 mmol) and powdered sodium hydroxide (0.8 20 mmol) were added, and the mixture was magnetically stirred for 4 - 5 h at room temperature. After addition of 300 mL of water to the mixture, the solution was stirred for 12 h at room temperature. The formed precipitate was collected by filtra- tion and washed several times with water. After drying under air, the formed product was recrystallized using methanol or ethanol to obtain the pure products. |