[ CAS No. 89598-97-0 ] {[proInfo.proName]}

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Quality Control of [ 89598-97-0 ]

COA NMR CNMR HPLC LC-MS

Related Doc. of [ 89598-97-0 ]

SDS Specification

Alternatived Products of [ 89598-97-0 ]

Product Details of [ 89598-97-0 ]

CAS No. :	89598-97-0	MDL No. :	MFCD00093408
Formula :	C₆H₆BBrO₃	Boiling Point :	-
Linear Structure Formula :	-	InChI Key :	XSXTWLOHAGPBNO-UHFFFAOYSA-N
M.W :	216.83	Pubchem ID :	44118764
Synonyms :

Safety of [ 89598-97-0 ]

Signal Word:	Warning	Class:	N/A
Precautionary Statements:	P261-P264-P270-P271-P280-P301+P312-P302+P352-P304+P340-P330-P363-P501	UN#:	N/A
Hazard Statements:	H302-H312-H332	Packing Group:	N/A
GHS Pictogram:

Application In Synthesis of [ 89598-97-0 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

Downstream synthetic route of [ 89598-97-0 ]

[ 89598-97-0 ] Synthesis Path-Downstream 1~1

1
[ 6287-82-7 ]
[ 89598-97-0 ]
4-bromo-2-(3-bromobenzo(b)thiophen-2-yl)phenol [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
78%	With tetrakis(triphenylphosphine) palladium(0); potassium carbonate; In 1,4-dioxane; water; at 90℃; for 6h;Schlenk technique;	accurate weighing 2, 3 - b bromophenylacetic and [b] Thiophene (600 mg, 2.0 mmol), 5 - bromo -2 - hydroxy phenyl boronic acid (418 mg, 1.0 mmol), and in turn to 25 ml of in shu Lunke bottle, adding potassium carbonate (828 mg, 6 mmol), four (triphenylphosphine) palladium (0.05 equivalent), 1, 4 - dioxane/water (volume ratio 4:1), is 90 C reaction in oil bath 6 hours. After the reaction, the solvent is removed under reduced pressure, the use of silica gel column separation, petroleum ether/ethyl acetate as eluant, to obtain 4 - bromo -2 - (3 - bromophenylacetic and [b] Thiophene -2 - yl) phenol 3h, and the yield is 78%.

Reference： [1]Patent: CN106883248,2017,A .Location in patent: Paragraph 0029; 0045
[2]Journal of Organic Chemistry,2017,vol. 82,p. 10920 - 10927

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Technical Information

? Acidity of Phenols ? Alkyl Halide Occurrence ? Appel Reaction ? Benzylic Oxidation ? Birch Reduction ? Blanc Chloromethylation ? Buchwald-Hartwig C-N Bond and C-O Bond Formation Reactions ? Chan-Lam Coupling Reaction ? Chugaev Reaction ? Corey-Kim Oxidation ? Dess-Martin Oxidation ? Electrophilic Substitution of the Phenol Aromatic Ring ? Etherification Reaction of Phenolic Hydroxyl Group ? Friedel-Crafts Reaction ? General Reactivity ? Grignard Reaction ? Halogenation of Phenols ? Hiyama Cross-Coupling Reaction ? Hydride Reductions ? Hydrogenolysis of Benzyl Ether ? Jones Oxidation ? Kinetics of Alkyl Halides ? Kumada Cross-Coupling Reaction ? Martin's Sulfurane Dehydrating Reagent ? Mitsunobu Reaction ? Moffatt Oxidation ? Oxidation of Alcohols by DMSO ? Oxidation of Phenols ? Pechmann Coumarin Synthesis ? Preparation of Alcohols ? Preparation of Aldehydes and Ketones ? Preparation of Alkylbenzene ? Preparation of Amines ? Reactions of Alcohols ? Reactions of Alkyl Halides with Reducing Metals ? Reactions of Amines ? Reactions of Benzene and Substituted Benzenes ? Reactions of Dihalides ? Reactions with Organometallic Reagents ? Reimer-Tiemann Reaction ? Ritter Reaction ? Sharpless Olefin Synthesis ? Stille Coupling ? Substitution and Elimination Reactions of Alkyl Halides ? Suzuki Coupling ? Swern Oxidation ? Vilsmeier-Haack Reaction

Historical Records

Related Functional Groups of
[ 89598-97-0 ]

Organoboron

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[ CAS No. 89598-97-0 ] {[proInfo.proName]}

Quality Control of [ 89598-97-0 ]

Related Doc. of [ 89598-97-0 ]

Product Details of [ 89598-97-0 ]

Safety of [ 89598-97-0 ]

Application In Synthesis of [ 89598-97-0 ]

[ 89598-97-0 ] Synthesis Path-Downstream 1~1

Technical Information

Related Functional Groups of [ 89598-97-0 ]

Organoboron

Aryls

Bromides

Precautionary Statements-General

Prevention

Response

Storage

Disposal

Physical hazards

Health hazards

Environmental hazards

Inquiry

Related Functional Groups of
[ 89598-97-0 ]