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CAS No. : | 873397-34-3 | MDL No. : | MFCD04114349 |
Formula : | C6H10O3 | Boiling Point : | No data available |
Linear Structure Formula : | - | InChI Key : | YEWPVCUHKJABMV-UHFFFAOYSA-N |
M.W : | 130.14 | Pubchem ID : | 16767361 |
Synonyms : |
|
Signal Word: | Warning | Class: | |
Precautionary Statements: | P261-P305+P351+P338 | UN#: | |
Hazard Statements: | H302-H315-H319-H335 | Packing Group: | |
GHS Pictogram: |
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* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
With hydrogen;Pd/C (30%); In ethanol; at 20℃; for 48h; | Synthesis of tetrahydro-2H-pyran-3-carboxylic acid:<strong>[40915-37-5]3,4-dihydro-2H-pyran-5-carboxylic acid</strong> (5.0 g, 39 mmol) was hydrogenated with H2 under Pd/C (30percent, 500 mg) in EtOH (100 mL) for 2 days at room temperature. The solution was filtered, EtOH was evaporated, and crude tetrahydro-2H-pyran-3-carboxylic acid (4.5 g) was used for next step without purification. 1H NMR (300 MHz, CDCI3/TMS): delta 11.0 (br s, 1H), 4.00 (m, 1H), 3.78 (m, 1H), 3.60 (1H), 3.45 (m, 1H), 2.59 (m, 1H), 1.99 (m, 1H), 1.76-1.59 (m, 3H). | |
With Pd/C (30%); hydrogen; In ethanol; at 20℃; for 48h; | [0563] Synthesis of tetrahydro-2H-pyran-3-carboxylic acid: [0564] <strong>[40915-37-5]3,4-dihydro-2H-pyran-5-carboxylic acid</strong> (5.0 g, 39 mmol) was hydrogenated with H2 under Pd/C (30percent, 500 mg) in EtOH (100 mL) for 2 days at room temperature. The solution was filtered, EtOH was evaporated, and crude tetrahydro-2H-pyran-3-carboxylic acid (4.5 g) was used for next step without purification. 1H NMR (300 MHz, CDCI3/TMS): delta 11.0 (br s, 1H), 4.00 (m, 1H), 3.78 (m, 1H), 3.60 (1H), 3.45 (m, 1H), 2.59 (m, 1H), 1.99 (m, 1H), 1.76-1.59 (m, 3H). |
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