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CAS No. : | 864377-31-1 | MDL No. : | MFCD22200060 |
Formula : | C21H14BrN3 | Boiling Point : | No data available |
Linear Structure Formula : | - | InChI Key : | HNZUKQQNZRMNGS-UHFFFAOYSA-N |
M.W : | 388.26 | Pubchem ID : | 58943302 |
Synonyms : |
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Signal Word: | Warning | Class: | |
Precautionary Statements: | P261-P305+P351+P338 | UN#: | |
Hazard Statements: | H315-H319-H335 | Packing Group: | |
GHS Pictogram: |
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* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
62% | With tetrakis(triphenylphosphine) palladium(0); sodium carbonate; In ethanol; water; toluene; at 120℃; for 6h; | After introducing to a reaction vessel (4- (1-phenyl-1 H-benz [d] imidazol-2-yl) phenyl) boronic acid (5.4 g, 17.00 mmol) , 2- (3-bromophenyl) -4, 6-diphenyl-1, 3, 5-triazine (6 g, 15.45 mmol) , tetrakis (triphenylphosphine) palladium (0.6 g, 0.46 mmol) , sodium carbonate (4.1 g, 38.63 mmol) , toluene 78 mL, and ethanol 19 mL, distilled water 19 mL was added thereto, and the mixture was stirred at 120 for 6 hours. After completing the reaction, the mixture was washed with distilled water and extracted with ethyl acetate. The organic layer was dried with magnesium sulfate, and the solvent was removed with a rotary evaporator. The residue was purified with column chromatography to obtain compound B-105 (5.5 g, yield: 62) . |
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