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CAS No. : | 721-04-0 | MDL No. : | MFCD00156689 |
Formula : | C14H12O2 | Boiling Point : | - |
Linear Structure Formula : | C6H5COCH2OC6H5 | InChI Key : | KRSXGTAVHIDVPM-UHFFFAOYSA-N |
M.W : | 212.24 | Pubchem ID : | 222171 |
Synonyms : |
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Signal Word: | Warning | Class: | N/A |
Precautionary Statements: | P261-P302+P352-P305+P351+P338 | UN#: | N/A |
Hazard Statements: | H302-H315-H319 | Packing Group: | N/A |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
67% | With copper(l) iodide; oxygen; In 1,2-dichloro-ethane; at 100℃; for 16h; | Take a clean 8mL sealed micro-reaction bottle, add a small magnet, dry, add<strong>[42182-27-4]2-aminoisonicotinonitrile</strong> (71.5 mg, 0.6 mmol),2-phenoxyacetophenone (42.5 mg, 0.2 mmol),Cuprous iodide (0.01 mmol),1,2-dichloroethane (1.0 mL),After heating at 100 ° C for 16 hours under oxygen,The reaction mixture was isolated by column chromatography to give the title compound (42.0 mg, yield 67percent). |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
95% | With iodine; In 1,2-dichloro-ethane; at 100℃; for 0.5h; | General procedure: A dried glass reaction tube equipped with a magnetic stir bar was charged with 1 (106 mg, 0.5 mmol), 2 or 4 (141.2 mg, or 207 mg,1.5 mmol), I2 (254 mg, 1 mmol) in DCE (10 mL); stirred at 100 C for30 min. The solvent was evaporated under vacuum, and washed with saturated sodium thiosulfate solution, water, brine. The organic layer was dried over anhydrous Na2SO4, filtered, and concentrated to give the crude product, which was purified through flash column chromatography (ethyl acetate in petroleum ether) to give the desired product. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
99% | With iodine; In 1,2-dichloro-ethane; at 100℃; for 0.5h; | General procedure: A dried glass reaction tube equipped with a magnetic stir bar was charged with 1 (106 mg, 0.5 mmol), 2 or 4 (141.2 mg, or 207 mg,1.5 mmol), I2 (254 mg, 1 mmol) in DCE (10 mL); stirred at 100 C for30 min. The solvent was evaporated under vacuum, and washed with saturated sodium thiosulfate solution, water, brine. The organic layer was dried over anhydrous Na2SO4, filtered, and concentrated to give the crude product, which was purified through flash column chromatography (ethyl acetate in petroleum ether) to give the desired product. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
With 2,3-dicyano-5,6-dichloro-p-benzoquinone; In 2-methoxy-ethanol; at 120℃; for 24.0h;Sealed tube; | Put 0.1mmol oxidized lignin model substrate 1 in a 10mL pressure tube, add 0.01mmol HNO3, 1mL DMSO and 0.2mmol o-phenylenediamine 2,After tightening the cap, heat the resulting reaction solution (the concentration of oxidized lignin in the reaction solution is 0.1 mmol/mL) in an oil bath at 100C for 12 hours,The decomposition reaction is carried out. After the reaction is completed, the obtained product is taken out and the solvent is drained and separated by a column to obtain two nitrogen-containing heterocyclic products. |