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Chemical Structure| 6229-00-1 Chemical Structure| 6229-00-1
Chemical Structure| 6229-00-1

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CAS No.: 6229-00-1

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Product Details of [ 6229-00-1 ]

CAS No. :6229-00-1
Formula : C20H16Si
M.W : 284.43
SMILES Code : C#C[Si](C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3
MDL No. :MFCD00075453
InChI Key :WADKYPSVXRWORK-UHFFFAOYSA-N
Pubchem ID :642601

Safety of [ 6229-00-1 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H315-H319-H335
Precautionary Statements:P261-P305+P351+P338

Application In Synthesis of [ 6229-00-1 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 6229-00-1 ]

[ 6229-00-1 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 4805-22-5 ]
  • [ 6229-00-1 ]
  • C48H34S2Si2 [ No CAS ]
YieldReaction ConditionsOperation in experiment
40% With copper(l) iodide; diethylamine; In dichloromethane; at 20℃; for 4h;Schlenk technique; General procedure: To a Schlenk flask containing [(PMe3)2(Br)Pd-Y-Pd(Br)(PMe3)2] (0.335 g, 0.40 mmol)were added CH2Cl2 (20 mL), CuI (15.2 mg, 0.080 mmol), Et2NH (0.124 mL, 1.20 mmol)and HCC-SiPh3 (0.340 g, 1.20 mmol) in that order. After stirring for 4 h at room temperature,the solvent was removed completely and the remaining solid was extractedwith CH2Cl2/H2O. The collected dichloromethane layer was dried over anhydrous CaCl2and evaporated under vacuum to give crude solid, which was washed with hexane(6 mLx 3) to remove side products. The remaining solid was recrystallized fromCH2Cl2/hexane to give a white powder of trans-[Pd(CC-SiPh3)2(PMe3)2] (16, 0.405 g,61%). The organic compound was identified as the bithiophene by GC-MS. Complex16:
 

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