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CAS No. : | 6147-53-1 | MDL No. : | MFCD00149569 |
Formula : | C4H14CoO8 | Boiling Point : | - |
Linear Structure Formula : | - | InChI Key : | ZBYYWKJVSFHYJL-UHFFFAOYSA-L |
M.W : | 249.08 | Pubchem ID : | 61372 |
Synonyms : |
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Signal Word: | Danger | Class: | 9 |
Precautionary Statements: | P201-P261-P280-P284-P304+P340-P308+P313 | UN#: | 3077 |
Hazard Statements: | H302-H315-H317-H334-H341-H350-H360-H410 | Packing Group: | Ⅲ |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
With sodium hydroxide; In water; at 140℃; for 72h;Autoclave; | A mixture of <strong>[499-49-0]5-methylisophthalic acid</strong> (18.2 mg, 0.1 mmol),1,6-bis(triazol)hexane (22.0 mg, 0.1 mmol), Co(OAc)2¢4H2O(24.9 mg, 0.1 mmol), NaOH(4 mg, 0.1mmol), and H2O(12 mL) was placed into 25mL Teflon-lined autoclave andheated at 140C for 72 h. The autoclave was cooled over aperiod of 11 h at a rate 5C h1 to room temperature. Redcrystals of complex 1 were obtained. It was collected by filtration,and dried in air. Anal. Calcd. (percent) forC38H45Co2N16O4.5: C, 49.84; H, 4.95; N, 24.47. Found (percent):C, 49.80; H, 4.89; N, 24.42. IR (cm1):3119 (s), 2919(m),2850(m), 1614 (s), 1539 (s), 1383 (s), 1279 (m), 1131 (s), 778(s), 725 (s), 667 (s). |