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CAS No. : | 578-95-0 | MDL No. : | MFCD00005019 |
Formula : | C13H9NO | Boiling Point : | - |
Linear Structure Formula : | - | InChI Key : | FZEYVTFCMJSGMP-UHFFFAOYSA-N |
M.W : | 195.22 | Pubchem ID : | 2015 |
Synonyms : |
|
Chemical Name : | Acridin-9(10H)-one |
Signal Word: | Warning | Class: | N/A |
Precautionary Statements: | P261-P305+P351+P338 | UN#: | N/A |
Hazard Statements: | H315-H319-H335 | Packing Group: | N/A |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
72% | General procedure: Acridone (10) (195mg, 1mmol) was added portion wise to a stirred suspension of NaH (56mg, 1.2mmol, 50% of mineral oil) in dry DMF (10ml) at 0C. The reaction mixture was stirred for 2h. Afterward, 2-chloro-N-(substituted)phenyl acetamides 12a-o (2mmol) and KI (33.2mg, 0.2mmol) were added to the reaction mixture with stirring for different time intervals. After completion of the reaction (TLC), the reaction mixture was poured into crushed ice (50g) with constant stirring. The precipitated solid was collected and then extracted with chloroform. The combined organic extracts were washed with brine and water and finally dried with anhydrous sodium sulfate. Pure compounds were isolated after column chromatography and recrystallized from suitable solvent. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
56% | Under nitrogen protection,24.6 g (100 mmol) of the compound of the formula F-1 was added,Tetrahydrofuran 500mL,At -78 C, 63 mL of n-butyl lithium (1.6 M) was added dropwise.Low temperature reaction for 30 minutes,The temperature was raised to 30 C for 3 hours.Cool down again to -78 C,Add 500mL9(10H)-acridone (Formula A-1The compound shown) (0.2 M 9.5 g (100 mmol)), slowly warmed to 30 C,After reacting for 15 hours, the reaction was quenched by the addition of aqueous ammonium chloride solution and extracted with chloroform.Rotating to remove the solvent,Pass through a silica gel column to obtain 20.3 g of solid intermediate 3-1(yield 56%); |
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