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CAS No. : | 5724-56-1 | MDL No. : | MFCD00019744 |
Formula : | C9H9N | Boiling Point : | - |
Linear Structure Formula : | - | InChI Key : | ZEDPQIJYJCPIRM-UHFFFAOYSA-N |
M.W : | 131.17 | Pubchem ID : | 79802 |
Synonyms : |
|
Signal Word: | Warning | Class: | N/A |
Precautionary Statements: | P261-P305+P351+P338 | UN#: | N/A |
Hazard Statements: | H315-H319-H335 | Packing Group: | N/A |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
91% | Preparation of 2.3-dimethylbenzaldehydeDIBAL-H Toluene 2,3-Dimethylbenzonitrile (50.0 g, 381 mmol) was dissolved in 100 mL toluene. The solution was cooled in an ice bath to 5 0C. The solution was stirred as DibalH solution (476 mL of IM in toluene, 476 mmol) was added slowly keeping temperature below 21 0C. This solution was reverse quenched slowly into vigorously stirred 2N HCl (800 mL), keeping the temperature below 25 0C. The water layer was removed and organic layer was washed twice with 6N HCl. The organic layer was concentrated to pale yellow oil, 46.3g (91percent yield). |
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