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Han, Guanqun ; University of Cincinnati,2021.
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Abstract: Mankind's sustainable development not only requires the capture and conversion of renewable energies but also necessitates the production of chemical goods from renewable carbon sources. Biomass is the only accessible and renewable carbon source. One major class of biomass is degradative small molecules, among which 5-hydroxymethylfurfural (HMF) is considered as a platform chemical and it can serve as a starting material to produce various upgrading compounds, eg, the oxidation products, 2, 5-furan dicarboxylic acid (FDCA), and 2, 5-diformylfuran (DFF), can act as biopolymer precursors. In this dissertation, we successfully demonstrated that ultrathin Ni/CdS nanosheets can be efficient photocatalyst to produce value-added bioproducts (eg, furoic acid, DFF, and FDCA) from biomass-derived molecules. Even more desirable is that the oxidative biomass upgrading can be integrated with H2 production.
Purchased from AmBeed: 552-41-0 ; 1481-27-2 ; 3109-63-5 ; 1450-72-2 ; 705-15-7 ; 141-53-7 ; 51791-26-5
CAS No. : | 552-41-0 | MDL No. : | MFCD00008730 |
Formula : | C9H10O3 | Boiling Point : | - |
Linear Structure Formula : | HOC6H2(OCH3)(CH3)CHO | InChI Key : | UILPJVPSNHJFIK-UHFFFAOYSA-N |
M.W : | 166.17 | Pubchem ID : | 11092 |
Synonyms : |
2'-Hydroxy-4'-methoxyacetophenone;Peonol;NSC 401442
|
Chemical Name : | 1-(2-Hydroxy-4-methoxyphenyl)ethanone |
Signal Word: | Warning | Class: | N/A |
Precautionary Statements: | P261-P273-P280-P305+P351+P338 | UN#: | N/A |
Hazard Statements: | H302+H312+H332-H315-H319-H335-H412 | Packing Group: | N/A |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
40% | With triethylamine; In dichloromethane; at 20℃; | General procedure: To a solution of paeonol/2-hydroxy acetophenone/3-methoxyphenol (1/2/3, 1.0 mmol) and ethanesulfonyl chloride/arylsulfonyl chloride (7, 1.2 mmol) in dry dichloromethane (CH2Cl2, 10 ml) at room temperature, a solution of triethylamine (Et3N) (1.5 mmol) in dry CH2Cl2 (5 ml) was added dropwise for 10 min. When the reaction was completed by TLC analysis, the reaction mixture was diluted with water (15 ml), and extracted with CH2Cl2 (30 ml*3). Subsequently, the combined organic phasewas washed by saturated aq. brine (30 ml), dried over anhydrous Na2SO4, concentrated in vacuo, and purified by silica gel column chromatography to obtain title compounds. The data for 4a-p, 5a-p, and 6a-p are shown as follows. |