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CAS No. : | 5350-41-4 | MDL No. : | MFCD00011780 |
Formula : | C10H16BrN | Boiling Point : | - |
Linear Structure Formula : | - | InChI Key : | UUZYBYIOAZTMGC-UHFFFAOYSA-M |
M.W : | 230.15 | Pubchem ID : | 21449 |
Synonyms : |
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Signal Word: | Warning | Class: | N/A |
Precautionary Statements: | P261-P305+P351+P338 | UN#: | N/A |
Hazard Statements: | H315-H319-H335 | Packing Group: | N/A |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
98% | In tetrahydrofuran; ethanol; at 25℃; for 24h;Inert atmosphere; | General procedure: In analogy to literature4, to a solution of benzyl halide 9 (1 equiv.) in THF (50 ml/g benzyl halide) were added 1.5 equiv. of trimethylamine 10 (33 wtpercent in EtOH).The resulting solution was stirred at RT for 24 hours, during which the product precipitated asa white solid. The resulting suspension was cooled to 0 °C, filtrated, washed with ice-cold Et2O and dried in vacuo to yield benzyl ammonium salts 6 in the reported yields. |
90% | In ethanol; acetonitrile; | In ethanol30percent triethylamine (0.76 ml, 3.1 mmol)Was dissolved in acetonitrile (5 ml)Was treated with benzyl bromide (0.40 ml, 3.4 mmol).The residue was dissolved in chloroform,Purification by precipitation in ether gave 1 (0.693 g, 90percent) as a white powder. |