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CAS No. : | 52462-29-0 | MDL No. : | MFCD00064793 |
Formula : | C20H28Cl4Ru2 | Boiling Point : | - |
Linear Structure Formula : | [Ru2Cl4((CH3)2CHC6H4CH3)2] | InChI Key : | LAXRNWSASWOFOT-UHFFFAOYSA-J |
M.W : | 612.39 | Pubchem ID : | 10908223 |
Synonyms : |
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Signal Word: | Warning | Class: | N/A |
Precautionary Statements: | P273-P305+P351+P338 | UN#: | N/A |
Hazard Statements: | H315-H319-H412 | Packing Group: | N/A |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
72% | In tetrahydrofuran; at 20℃; for 2h;Inert atmosphere; | General procedure: A 50-mL round-bottom flask was charged with [Ru(p-cymene)Cl2]2 (0.2029 g, 0.331 mmol) and CH2Cl2(20 mL). To the orange solution was added P(C6H4F)3 (0.2199 g, 0.695 mmol), and the mixture was leftto stir for 3 h at room temperature. The volatiles were removed in vacuo to leave a dark red oil, andhexanes were added to precipitate a solid product. The resulting orange solid was collected by vacuumfiltration and dried in vacuo (0.3529 g, 86percent yield). |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
61.8% | In ethanol; at 20℃; for 2h; | To a warm solution of [Ru(eta6-p-cymene)Cl2]2 (61 mg, 0.1 mmol) in ethanol (5 ml) <strong>[6624-49-3]isoquinoline-3-carboxylic acid</strong> (HL7) (38 mg,0.2 mmol) in ethanol (3 ml) was added. The mixture was stirred at room temperature for 2 h. The yellow product was filtered off, washed with EtOH (5 ml) and dried in air. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
60% | With potassium acetate; In dichloromethane; at 20℃; for 20h;Inert atmosphere; Schlenk technique; | Dichloromethane (10 mL) was added to dichloro(pcymene)ruthenium(II) dimer (0.16 mmol) in a round bottom flask. To this solution were added, L6 (0.33 mmol) followed by potassium acetate(0.38 mmol). The reaction mixturewas stirred at room temperature for 20 h. Then the solvent was evaporated and the residue leftbehind was dissolved in dichloromethane and the mixture wasfiltered. The filtratewas then added to large volume of diethyl etherresulting in a precipitate which was filtered and washed withdiethyl ether and dried. (90 mg, 60percent yield) 1H NMR (CDCl3,400 MHz): delta 0.80 (3H, d, J 6.8 Hz, isopropyl), 0.94 (3H, d,J 6.8 Hz, isopropyl), 2.08 (3H, s, methyl), 2.31 (1H, m, isopropyl),4.10 (3H, s, N-methyl), 5.14 (1H, d, J 5.9 Hz, cymene), 5.36 (1H, d,J 5.9 Hz cymene), 5.70 (1H, d, J 5.9 Hz, cymene), 5.84 (1H, d,J 5.9 Hz, cymene) 7.07 (1H, m, ArH), 7.21 (1H, m, ArH), 7.40 (3H, m,ArH), 7.80 (1H, m, ArH), 7.9 (1H, d, J 7.6 Hz, ArH), 8.33 (1H, d,J 7.6 Hz, ArH). 13C NMR (CDCl3, 100 MHz): delta 19.42, 22.36, 23.08,31.35, 32.41, 81.77, 82.17, 89.26, 89.77, 99.43, 101.55, 110.27, 117.49,122.89, 123.48, 123.61, 124.80,129.36, 134.62, 136.74, 140.99, 141.84,158.86, 183.66. Elemental analysis for C24H25Cl1N2Ru, calcd. (percent) C,60.31; H, 5.27; N, 5.86. Found: C, 60.16; H, 5.14; N, 5.90. |