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CAS No. : | 40180-80-1 | MDL No. : | MFCD02683854 |
Formula : | C9H9BrO | Boiling Point : | - |
Linear Structure Formula : | - | InChI Key : | PDJLFESXPVLVMR-UHFFFAOYSA-N |
M.W : | 213.07 | Pubchem ID : | 3309401 |
Synonyms : |
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Signal Word: | Warning | Class: | N/A |
Precautionary Statements: | P261-P305+P351+P338 | UN#: | N/A |
Hazard Statements: | H302-H315-H319 | Packing Group: | N/A |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
1.99 g | With nido-decaborane; In methanol; at 20℃; for 12h; | Step 1 (0642) To a mixture of 1-(3-bromo-4-methylphenyl)ethanone (1.51 g), <strong>[7149-75-9]4-chloro-3-methylphenylamine</strong> (1.0 g) and methanol (14 mL) was added decaborane (259 mg), and the mixture was stirred at room temperature for 12 hours. After the mixture was diluted with ethyl acetate, to the resulting mixture was added aminopropyl silica gel powder (5 g). The resulting mixture was filtered and the filtrate was concentrated under reduced pressure to give [1-(3-bromo-4-methylphenyl)ethyl]-(4-chloro-3-methylphenyl)amine (1.99 g). |