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CAS No. : | 3615-41-6 | MDL No. : | MFCD00066373 |
Formula : | C6H12O5 | Boiling Point : | No data available |
Linear Structure Formula : | - | InChI Key : | - |
M.W : | 164.16 | Pubchem ID : | - |
Synonyms : |
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Chemical Name : | (2R,3R,4S,5S)-2,3,4,5-Tetrahydroxyhexanal |
Signal Word: | Warning | Class: | |
Precautionary Statements: | P261-P305+P351+P338 | UN#: | |
Hazard Statements: | H315-H319-H335 | Packing Group: | |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
With sulfuric acid; water; at 80℃; for 2h; | A MeOH solution of 1 (3 mg) was treated with H2SO4 solution (5%), hydrolyzed on a waterbath at 80 C for 2 h, cooled, diluted with H2O, and extracted with EtOAc. The extract was washed with H2O, dried over anhydrous Na2SO4, and evaporated to dryness. The solid was dissolved in MeOH, after which the aglycon crystallized, mp 325-330. UV spectrum (a, lambdamax, nm): 265, 345; +NaOMe - 267, 405; +AlCl3 - 274, 396; + AlCl3/HCl - 275,394; + NaOAc - 274, 355. The aqueous fraction was neutralized by AV-17 anion-exchanger (OH--form). Sugars were identified by comparing paper chromatograms with authentic D-glucose and L-rhamnose using system 3. |