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CAS No. : | 35202-55-2 | MDL No. : | MFCD28038688 |
Formula : | C11H16ClNO2 | Boiling Point : | No data available |
Linear Structure Formula : | - | InChI Key : | UWGJJMDXKWGAED-UHFFFAOYSA-N |
M.W : | 229.70 | Pubchem ID : | 20058493 |
Synonyms : |
|
Signal Word: | Warning | Class: | |
Precautionary Statements: | P261-P280-P305+P351+P338 | UN#: | |
Hazard Statements: | H302-H315-H319-H332-H335 | Packing Group: | |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
90% | Based on EP 0 534 859 Step 1: 3,4-dimethoxybicyclo[4.2.0]octa-1,3,5-trien-7-amine hydrochloride [0053] 312 mL of a molar solution of borane complexed with THF are added dropwise, and whilst stirring at ambient temperature, to a solution of 25 g of <strong>[35202-54-1]3,4-dimethoxybicyclo[4.2.0]octa-1,3,5-triene-7-carbonitrile</strong> in 250 mL of THF and left in contact for 12 hours; 200 mL of ethanol are then added and stirring is carried out for 1 hour. 100 mL of 3.3N ethereal HCl are added dropwise. 27.7 g of the expected product are obtained. [0054] Yield=90percent [0055] m.p.=205° C. | |
90% | Step 1: 3,4-dimethoxybicyclo[4.2.0]octa-1,3,5-trien-7-amine hydrochloride 312 mL of a molar solution of borane complexed with THF are added dropwise, and whilst stiffing at ambient temperature, to a solution of 25 g of <strong>[35202-54-1]3,4-dimethoxybicyclo[4.2.0]octa-1,3,5-triene-7-carbonitrile</strong> in 250 mL of THF and left in contact for 12 hours; 200 mL of ethanol are then added and stirring is carried out for 1 hour. 100 mL of 3.3N ethereal HCl are added dropwise. 27.7 g of the expected product are obtained. Yield=90percent m.p.=205° C. | |
90% | 312 mL of a molar solution of borane complexed with THF are added dropwise, and whilst stiffing at ambient temperature, to a solution of 25 g of <strong>[35202-54-1]3,4-dimethoxybicyclo[4.2.0]octa-1,3,5-triene-7-carbonitrile</strong> in 250 mL of THF and left in contact for 12 hours; 200 mL of ethanol are then added and stirring is carried out for 1 hour. 100 mL of 3.3N ethereal HC1 are added dropwise. 27.7 g of the expected product are obtained. [0042] Yield=90percent [0043] m.p.=205° C. |
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