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CAS No. : | 3262-89-3 | MDL No. : | MFCD00014587 |
Formula : | C18H15B3O3 | Boiling Point : | - |
Linear Structure Formula : | (OBC6H5)3 | InChI Key : | VOXXGUAZBWSUSS-UHFFFAOYSA-N |
M.W : | 311.74 | Pubchem ID : | 72595 |
Synonyms : |
|
Signal Word: | Warning | Class: | N/A |
Precautionary Statements: | P261-P301+P312-P302+P352-P304+P340-P305+P351+P338 | UN#: | N/A |
Hazard Statements: | H302-H315-H319-H335 | Packing Group: | N/A |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
76% | With palladium(II) trifluoroacetate; silver carbonate; glyoxal bis(N-methyl-N-phenylhydrazone); In dimethyl sulfoxide; at 80℃; for 2h; | General procedure: To a mixture of arylcarboxylic acid (0.20 mmol), Ag2CO3 (165 mg, 0.60 mmol), Pd(TFA)2 (5.0 mg, 0.015 mmol, 7.5 mol %), and ligand 1d (4.0 mg, 0.015 mmol, 7.5 mol %) in DMSO (1.0 mL) was addedarylboroxin (0.40 mmol) at room temperature under an atmosphere of air.After the mixture was stirred at 80?C for 2 h, the mixture was diluted withethyl acetate and water. The organic layer was washed with brine, dried overMgSO4, and concentrated under reduced pressure. The residue was purified by silica gel chromatography (hexane/EtOAc = 20:1). |
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