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Structure of 32333-53-2

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CAS No.: 32333-53-2

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Quality Control of [ 32333-53-2 ] Purity: 98% SDS Specification

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Product Details of [ 32333-53-2 ]

CAS No. :	32333-53-2
Formula :	C₇H₃Cl₂F₃O₂S
M.W :	279.06
SMILES Code :	O=S(C1=CC=C(Cl)C(C(F)(F)F)=C1)(Cl)=O
MDL No. :	MFCD00024882
InChI Key :	SSULGNXFUGLULI-UHFFFAOYSA-N
Pubchem ID :	2780719

Safety of [ 32333-53-2 ]

GHS Pictogram:
Signal Word:	Danger
Hazard Statements:	H290-H314
Precautionary Statements:	P234-P260-P264-P280-P301+P330+P331+P310-P303+P361+P353+P310+P363-P304+P340+P310-P305+P351+P338+P310-P390-P405-P406-P501
Class:	8
UN#:	3261
Packing Group:	Ⅱ

Application In Synthesis of [ 32333-53-2 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

Downstream synthetic route of [ 32333-53-2 ]

[ 32333-53-2 ] Synthesis Path-Downstream 1~3

1
[ 445-13-6 ]
[ 32333-53-2 ]

Yield	Reaction Conditions	Operation in experiment
		Following the procedure of N. Ikemoto et al. (Tetrahedron, 59:1317 (1998)), <strong>[445-13-6]3-chloro-4-trifluoromethylaniline</strong> (890 mg, 4.6 mmol, Ryan Scientific) in CH3CN (37 mL) was added to a 250 mL round-bottomed flask. The flask was cooled in an ice bath, and HOAc (3.7 mL) and HCl (12 M, 1.8 mL) were added. Sodium nitrite (380 mg, 5.5 mmol, Aldrich) in 0.77 mL of H2O was added in 0.15 mL portions every 2 min until all of the solution had been added (total time ca. 9 min). After 25 min, sulfur dioxide (Aldrich) was bubbled into the reaction mixture for 1.25 h. Copper(II)chloride (780 mg, 5.8 mmol, Aldrich) in 1.5 mL of water was then added to the reaction mixture. Gas evolution occurred, and the reaction was warmed to RT and stirred overnight. After the lower boiling solvents were removed in vacuo, water was added, and the mixture was extracted with CH2Cl2 (3×). The combined organic layers were washed with water, dried over MgSO4, filtered and concentrated in vacuo to give the crude material as a brownish oil with solid in it. The compound did not ionize well, but an aliquot, when treated with propylamine, provided the propylarylsulfonamide adduct with a ESI-MS, -ion, m/z=300.2 (M-1).

References: [1]Patent: US2005/234044,2005,A1 .Location in patent: Page/Page column 42-43.

2
[ 32333-53-2 ]
[ 6397-33-7 ]
4-Chloro-3-trifluoromethyl-2-isopropylthiobenzensulfonanilide [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
		Example 12 4-Chloro-3-trifluoromethyl-2--isopropylthiobenzensulfonanilide (Compound No. 66) The procedure of Example 10 was repeated using 16.7 g of <strong>[6397-33-7]2-isopropylthioaniline</strong> and 27.9 g of 4-chloro-3-trifluoromethylbenzenesulfonyl chloride to yield 37.7 g of the title compound as a brown oil. Purification by silicagel-colum chromatography gave a colorless oil, n [23/D ] =1.5518.

References: [1]Patent: EP306222,1989,A3 .

3
[ 445-13-6 ]
[ 7446-09-5 ]
[ 32333-53-2 ]

Yield	Reaction Conditions	Operation in experiment
		Following the procedure of N. Ikemoto et al. (Tetrahedron, 59 : 1317 (1998)), <strong>[445-13-6]3-chloro-4-trifluoromethylaniline</strong> (890 mg, 4.6 mmol, Ryan Scientific) in CH3CN (37 mL) was added to a 250 mL round-bottomed flask. The flask was cooled in an ice bath, and HOAc (3.7 mL) and HCl (12 M, 1.8 mL) were added. Sodium nitrite (380 mg, 5.5 mmol, Aldrich) in 0.77 mL of H2O was added in 0.15 mL portions every 2 min until all of the solution had been added (total time ca. 9 min). After 25 min, sulfur dioxide (Aldrich) was bubbled into the reaction mixture for 1.25 h. Copper (II) chloride (780 mg, 5.8 mmol, Aldrich) in 1.5 mL of water was then added to the reaction mixture. Gas evolution occurred, and the reaction was warmed to RT and stirred overnight. After the lower boiling solvents were removed in vacuo, water was added, and the mixture was extracted with CH2Cl2 (3x). The combined organic layers were washed with water, dried over MgSO4, filtered and concentrated in vacuo to give the crude material as a brownish oil with solid in it. The compound did not ionize well, but an aliquot, when treated with propylamine, provided the propylarylsulfonamide adduct with a ESI-MS,-ion, M/Z = 300.2 (M-1).

References: [1]Patent: WO2004/92164,2004,A1 .Location in patent: Page 123; 124.

Historical Records

Technical Information

? Alkyl Halide Occurrence ? Benzylic Oxidation ? Birch Reduction ? Blanc Chloromethylation ? Friedel-Crafts Reaction ? General Reactivity ? Grignard Reaction ? Hiyama Cross-Coupling Reaction ? Hydrogenolysis of Benzyl Ether ? Kinetics of Alkyl Halides ? Kumada Cross-Coupling Reaction ? Preparation of Alkylbenzene ? Reactions of Alkyl Halides with Reducing Metals ? Reactions of Amines ? Reactions of Benzene and Substituted Benzenes ? Stille Coupling ? Substitution and Elimination Reactions of Alkyl Halides ? Suzuki Coupling ? Vilsmeier-Haack Reaction

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[ 32333-53-2 ]

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