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CAS No. : | 2973-77-5 | MDL No. : | MFCD00016980 |
Formula : | C7H4Br2O2 | Boiling Point : | No data available |
Linear Structure Formula : | - | InChI Key : | SXRHGLQCOLNZPT-UHFFFAOYSA-N |
M.W : | 279.91 | Pubchem ID : | 18100 |
Synonyms : |
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Signal Word: | Warning | Class: | |
Precautionary Statements: | P261-P305+P351+P338 | UN#: | |
Hazard Statements: | H315-H319-H335 | Packing Group: | |
GHS Pictogram: |
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* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
97% | With piperidine; In methanol; at 100.0℃; for 0.5h;Microwave irradiation; | General procedure: Equimolar amounts (0.3 mmol) of 5-chlorooxindole/oxindole and aldehyde were dissolved in methanol (1 ml), a drop of piperidine (30 μl) was added and the mixture heated at 100C under microwave irradiation for 30 min. The reaction mixture was cooled to room temperature and the resulting precipitate was removed by filtration, carefully washed with methanol and recrystallized at least once from methanol to give the desired product in good yield. |
97% | With pyridine; In methanol; at 100.0℃; for 0.5h;Microwave irradiation; | General procedure: A suspension of indolinone (0.3mmol), aldehyde (0.3mmol) and pyridine (30μL) in methanol (1mL) were heated under microwave irradiation at 100 C for 30 minutes. The reaction mixture was cooled to room temperature and the resulting precipitate was removed by filtration, carefully washed with methanol and dried in vacuo. When no precipitate was observed methanol was removed under vacuum and the residue was purified by silica gel chromatography to give the desired product. |
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