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CAS No. : | 2973-50-4 | MDL No. : | MFCD00091082 |
Formula : | C8H8N2 | Boiling Point : | No data available |
Linear Structure Formula : | - | InChI Key : | LMDPYYUISNUGGT-UHFFFAOYSA-N |
M.W : | 132.16 | Pubchem ID : | 76307 |
Synonyms : |
|
Signal Word: | Warning | Class: | |
Precautionary Statements: | P280 | UN#: | |
Hazard Statements: | H302-H312-H332 | Packing Group: | |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
90.7% | With 4,4'-dimethyl-2,2'-bipyridines; palladium(II) acetylacetonate; toluene-4-sulfonic acid; In water; at 90℃; for 20h;Inert atmosphere; | To a suitable amount of water at room temperature was added 100 mmol of the compound of the above formula (I), 250 mmol of the compound of the above formula (II)5 mmol of palladium acetylacetonate (Pd (acac) 2), 20 mmol of nitrogen-containing ligand L1 and 600 mmol of acid promoter p-toluenesulfonic acid monohydrate were charged and then purged with nitrogen keeping the reaction atmosphere inert.Stirring heated to 90 ,And the reaction was stirred at this temperature for 20 hours; After the reaction was completed, the mixture was poured into ethyl acetate and washed successively with saturated aqueous NaHCO 3 and brine. The aqueous layer was separated and the aqueous layer was extracted with ethyl acetate. The organic layers were combined (that is, the combined organic layer was washed and extracted ), Dried over anhydrous Na2SO4 and the solvent removed under reduced pressure. The residue was purified by flash column chromatography (petroleum ether / ethyl acetate, 8: 1 by volume) to give the title compound of the above formula (III) compound in 90.7% yield. |
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