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CAS No. : | 2270-20-4 | MDL No. : | MFCD00004416 |
Formula : | C11H14O2 | Boiling Point : | No data available |
Linear Structure Formula : | C6H5CH2CH2CH2CH2COOH | InChI Key : | BYHDDXPKOZIZRV-UHFFFAOYSA-N |
M.W : | 178.23 | Pubchem ID : | 16757 |
Synonyms : |
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Chemical Name : | 5-Phenylvaleric Acid |
Signal Word: | Warning | Class: | |
Precautionary Statements: | P261-P305+P351+P338 | UN#: | |
Hazard Statements: | H315-H319-H335 | Packing Group: | |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
69% | Example 46: 3-l(5-phenylpentanoyl)aminol-4-pyridinecarboxylic acid DMF (0.05m1) was added dropwise over lOs to a solution of 5-phenylpentanoic acid (387 mg, 2.17 mmol) and oxalyl chloride (0.238 ml, 2.71 mmol) in DCM (5 ml) under nitrogen. The reaction mixture was stirred at room temperature for 2 h then concentrated in vacuo to give a yellow oil. The oil was dissolved in DMF (1 ml) then added dropwise to a stirred suspension of 3-amino-4-pyridinecarboxylic acid (250 mg, 1 .81 mmol) in DMF (4 mL) at 0 °C under nitrogen. After 5 mm stirring the reactionmixture was allowed to warm to room temperature over 1 h then filtered through a plug of cotton wool. Water (10 ml) was added to the filtrate and the resultant suspension stirred for 15 mm then filtered, washed with water (100 ml), then methanol (100 ml), then ether (100 ml). The solid was dried in vacuo to give the title compound as a white solid (370mg, 69percent).1H NMR (400 MHz, DMSO-6) 10.S9ppm (1H, brs), 9.4oppm (1H, 5), 8.41 ppm (1H, d), 7.75ppm (1H, d), 7.32-7.1 3ppm (5H, m), 2.61 ppm (2H, t), 2.44ppm (2H, t), 1 .72-1 .Soppm (4H, m).LCMS (Method A): Rt = 0.75 mins, MH+ = 299.1 |