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CAS No. : | 2247-88-3 | MDL No. : | MFCD00234072 |
Formula : | C5H5FN2 | Boiling Point : | No data available |
Linear Structure Formula : | - | InChI Key : | UFIKBUVVVGSMGW-UHFFFAOYSA-N |
M.W : | 112.11 | Pubchem ID : | 817122 |
Synonyms : |
|
Signal Word: | Warning | Class: | |
Precautionary Statements: | P261-P305+P351+P338 | UN#: | |
Hazard Statements: | H302-H315-H319-H335 | Packing Group: | |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
With palladium 10% on activated carbon; hydrogen; In methanol; at 25℃; under 760.051 Torr; | Example 4 (0055) Catalytic hydrogenation of 3-fluoro-4-nitropyridine N-oxide (9): 0.1 mg of 3-fluoro-4-aminopyridine N-oxide (9) was dissolved in 4 mL of MeOH in a 50 mL round bottom flask containing a stir bar. While stirring, 3-4 mg of 10percent Pd/C (dry basis) was added and the flask sealed with a rubber septum. The vial was evacuated and backfilled with hydrogen gas from a balloon and the mixture was allowed to react for 10 min. After 10 min, the suspension was passed through a 0.4 m PTFE filter and analyzed by HPLC (conditions C). Reference retention times: 3-fluoro-4-aminopyridine N-oxide (9)=5.80 min, 3-fluoro-4-aminopyridine (10)=7.05 min. Retention time for the product matched within 0.05 min the reference standard. Identity of the product was confirmed by HR-MS (m/z M+ exp.: 112.0416, calc: 112.0437). Product amount was calculated from the area under the curve of the HPLC UV2 trace using a calibration curve. |
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