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CAS No. : | 2060-64-2 | MDL No. : | MFCD04974042 |
Formula : | C9H6O2S | Boiling Point : | No data available |
Linear Structure Formula : | - | InChI Key : | SNBYTKLWZRHESA-UHFFFAOYSA-N |
M.W : | 178.21 | Pubchem ID : | 2795444 |
Synonyms : |
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Signal Word: | Warning | Class: | |
Precautionary Statements: | P305+P351+P338 | UN#: | |
Hazard Statements: | H302-H319 | Packing Group: | |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
With lithium aluminium tetrahydride; In tetrahydrofuran; at 0℃;Inert atmosphere; | To a solution of benzo[b]thiophene-5-carboxylic acid (LXIX) (0.9 g, 5.1 mmol) in THF (20 mL) was added LAH (0.28 g, 7 mmol) in portions at 0 C. under nitrogen atmosphere. The reaction was quenched by water, washed with 20% aq. NaOH (4 mL) and extracted with EtOAc. The EtOAc phase was concentrated in vacuo to give the crude benzo[b]thiophen-5-ylmethanol (LXX) as yellow solid. (1 g, used without further purification) ESIMS found C9H8OS m/z 165.0 (M+H). |
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